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Nanosystems: Physics, Chemistry, Mathematics, 2019, Volume 10, Issue 5, Pages 585–598
DOI: https://doi.org/10.17586/2220-8054-2019-10-5-585-598 (Mi nano473) 		 
This article is cited in 2 scientific papers (total in 2 papers)

CHEMISTRY AND MATERIAL SCIENCE

Hydrophobization of up-conversion luminescent films based on nanocellulose/MF$_2$:HO particles (M = Sr, Ca) by acrylic resin

A. A. Lugininaa, S. V. Kuznetsova, V. V. Voronova, A. D. Yapryntsevb, V. K. Ivanovb, D. I. Petukhovc, A. A. Lyapind, A. S. Ermakovd, D. V. Pominovaa, E. V. Chernovaa, A. A. Pynenkovd, K. N. Nishchevd, P. P. Fedorova

a Prokhorov General Physics Institute of the Russian Academy of Sciences, Vavilov str. 38, Moscow, 119991, Russia
b Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninskii prosp. 31, Moscow, 119991, Russia
c Lomonosov Moscow State University, Chemical department, Leninskie Gory str. 1, Moscow, 119991, Russia
d Ogarev Mordovia State University, Bolshevistskaya str. 68, Saransk, 430005, Russia
Full-text PDF (4311 kB) Citations (2)
DOI: https://doi.org/10.17586/2220-8054-2019-10-5-585-598
Abstract: Luminescent hydrophobic composite films based on nanocrystalline (CNC) and nanofibrillated (CNF) cellulose matrix with up-conversion MF$_2$:Ho (M = Ca, Sr) particles and acrylic resin (ACR) as a coating have been synthesized. Flexible, translucent composite films were obtained by molding from the CNC/CNF suspensions with up-conversion particles. ACR coating was applied to the composite film by spraying. Studies have shown that ACR coating with a layer thickness of 7–10 $\mu$m provides hydrophobic properties for the films, increasing the water contact angle up to 100$\pm$2$^\circ$ with a simultaneous improvement in the luminescent properties. Transparency of CNC/CNF/MF$_2$:Ho-ACR films in the visible and near IR region improves by 20–25% without compromising the flexibility and thermal stability. The manufactured water-resistant composite films can be utilized as potential photonics materials, in particular for visualization of near-IR laser radiation and luminescent labels.
Keywords: cellulose nanocrystals, cellulose nanofibrils, nanocomposites, hydrophobicity, acrylic resins, SrF$_2$:HO, CaF$_2$:HO, up-conversion luminescence films.
Funding agency Grant number
Russian Foundation for Basic Research 16-29-11784-ofi-m
The study was funded by the Russian Foundation for Basic Research (RFBR 16-29-11784-ofi-m).
Received: 01.10.2019
Revised: 04.10.2019
Bibliographic databases:
Document Type: Article
Language: English
Citation: A. A. Luginina, S. V. Kuznetsov, V. V. Voronov, A. D. Yapryntsev, V. K. Ivanov, D. I. Petukhov, A. A. Lyapin, A. S. Ermakov, D. V. Pominova, E. V. Chernova, A. A. Pynenkov, K. N. Nishchev, P. P. Fedorov, “Hydrophobization of up-conversion luminescent films based on nanocellulose/MF$_2$:HO particles (M = Sr, Ca) by acrylic resin”, Nanosystems: Physics, Chemistry, Mathematics, 10:5 (2019), 585–598
Citation in format AMSBIB
\Bibitem{LugKuzVor19}
\by A.~A.~Luginina, S.~V.~Kuznetsov, V.~V.~Voronov, A.~D.~Yapryntsev, V.~K.~Ivanov, D.~I.~Petukhov, A.~A.~Lyapin, A.~S.~Ermakov, D.~V.~Pominova, E.~V.~Chernova, A.~A.~Pynenkov, K.~N.~Nishchev, P.~P.~Fedorov
\paper Hydrophobization of up-conversion luminescent films based on nanocellulose/MF$_2$:HO particles (M = Sr, Ca) by acrylic resin
\jour Nanosystems: Physics, Chemistry, Mathematics
\yr 2019
\vol 10
\issue 5
\pages 585--598
\mathnet{http://mi.mathnet.ru/nano473}
\crossref{https://doi.org/10.17586/2220-8054-2019-10-5-585-598}
\isi{https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Publons&SrcAuth=Publons_CEL&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=000495968100011}
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