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This article is cited in 2 scientific papers (total in 2 papers)
CHEMISTRY AND MATERIAL SCIENCE
Synthesis and down-conversion luminescence of Ba$_4$Y$_3$F$_{17}$:Yb:Pr solid solutions for photonics
S. V. Kuznetsova, A. S. Nizamutdinovb, M. N. Mayakovaa, V. V. Voronova, E. I. Madirovb, A. R. Khadievb, D. A. Spasskyc, I. A. Kamenskikhd, A. D. Yapryntseve, V. K. Ivanove, M. A. Marisovb, V. V. Semashkob, P. P. Fedorova a Prokhorov General Physics Institute of the Russian Academy of Sciences,
38 Vavilov str., Moscow, 119991 Russia
b Kazan Federal University, 18 Kremljovskaya, Kazan, 420008 Russia
c Skobeltsyn Institute of Nuclear Physics, Lomonosov Moscow State University,
Leninskie Gory, Moscow 119991, Russia
d Physics Faculty of Lomonosov Moscow State University, Leninskie Gory, Moscow 119991, Russia
e Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences,
31 Leninsky pr., Moscow,119991 Russia
Abstract:
Singlephase powders of Ba$_4$Y$_3$F$_{17}$:Yb:Pr solid solutions with an average agglomerate size of 400 nm were synthesized by coprecipitation from aqueous solutions. It was shown that the down-conversion mechanism in the investigated samples was quantum cutting, with one photon absorbed by Pr$^{3+}$ ions resulting in two photons emitted by Yb$^{3+}$ ions. At first, overall the external quantum yield of down-conversion luminescence measured appeared to be relatively high, with a maximum value of 2.9 % for the Ba$_{4}$Y$_{3}$F$_{17}$: Pr(0.1 %):Yb(10 %) sample. It makes this compound promising for Si-based solar cells efficiency enhancement.
Keywords:
synthesis, down-conversion, luminescence, solid solutions, photonics, fluorides.
Received: 02.03.2019
Citation:
S. V. Kuznetsov, A. S. Nizamutdinov, M. N. Mayakova, V. V. Voronov, E. I. Madirov, A. R. Khadiev, D. A. Spassky, I. A. Kamenskikh, A. D. Yapryntsev, V. K. Ivanov, M. A. Marisov, V. V. Semashko, P. P. Fedorov, “Synthesis and down-conversion luminescence of Ba$_4$Y$_3$F$_{17}$:Yb:Pr solid solutions for photonics”, Nanosystems: Physics, Chemistry, Mathematics, 10:2 (2019), 190–198
Linking options:
https://www.mathnet.ru/eng/nano432 https://www.mathnet.ru/eng/nano/v10/i2/p190
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