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Nanosystems: Physics, Chemistry, Mathematics, 2018, Volume 9, Issue 3, Pages 410–416
DOI: https://doi.org/10.17586/2220-8054-2018-9-3-410-416 (Mi nano324) 		 
This article is cited in 8 scientific papers (total in 8 papers)

CHEMISTRY AND MATERIAL SCIENCE

On an adsorption/photocatalytic performance of nanotubular Mg3Si2O5(OH)4/TiO2 composite

A. A. Krasilinab, I. S. Bodalyovc, A. A. Malkovc, E. K. Khrapovab, T. P. Maslennikovad, A. A. Malyginc

a Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninsky prospect, Moscow 119991, Russia
b Ioffe Institute, 26 Politekhnicheskaya street, St. Petersburg, 194021, Russia
c Saint-Petersburg State Institute of Technology, 26 Moskovskiy Prospekt, St. Petersburg 190013, Russia
d Institute of Silicate Chemistry, Russian Academy of Sciences, 2 Naberezhnaya Admirala Makarova, St. Petersburg 199034, Russia
Full-text PDF (616 kB) Citations (8)
DOI: https://doi.org/10.17586/2220-8054-2018-9-3-410-416
Abstract: Here, we study a performance of nanotubular Mg3Si2O5(OH)4/TiO2 hybrid adsorbent/photocatalyst in the process of decolorizing an aqueous solution of crystal violet. The composite material was produced by hydrothermal treatment with one or more subsequent cycles of TiCl4 treatment and vapor-phase hydrolysis according to the molecular layering technique. Decolorization was observed in situ by UV-VIS spectroscopy. It was found that TiO2 deposition yields 2 to 3 times improvement of decolorization performance. Depending on TiO2 phase type - amorphous or crystalline - this rise is related with either enhancement of adsorption rate either appearance of photocatalytic activity. Finally, fitting procedure issues in case of complex decolorization process were discussed.
Keywords: chrysotile nanotubes, titanium tetrachloride, titanium oxide, crystal violet dye, adsorption, photocatalysis, water remediation.
Funding agency Grant number
Russian Science Foundation 17-73-10426
The research was supported by Russian Science Foundation grant 17-73-10426. The SEM research was performed using the equipment of the JRC PMR IGIC RAS. The XRPD study was performed using the equipment of the Engineering Centre of Saint Petersburg State Technological Institute (Technical University).
Received: 01.04.2018
Revised: 08.05.2018
Bibliographic databases:
Document Type: Article
PACS: 68.43.Mn, 82.65.+r
Language: English
Citation: A. A. Krasilin, I. S. Bodalyov, A. A. Malkov, E. K. Khrapova, T. P. Maslennikova, A. A. Malygin, “On an adsorption/photocatalytic performance of nanotubular Mg3Si2O5(OH)4/TiO2 composite”, Nanosystems: Physics, Chemistry, Mathematics, 9:3 (2018), 410–416
Citation in format AMSBIB
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\by A.~A.~Krasilin, I.~S.~Bodalyov, A.~A.~Malkov, E.~K.~Khrapova, T.~P.~Maslennikova, A.~A.~Malygin
\paper On an adsorption/photocatalytic performance of nanotubular Mg$_3$Si$_2$O$_5$(OH)$_4$/TiO$_2$ composite
\jour Nanosystems: Physics, Chemistry, Mathematics
\yr 2018
\vol 9
\issue 3
\pages 410--416
\mathnet{http://mi.mathnet.ru/nano324}
\crossref{https://doi.org/10.17586/2220-8054-2018-9-3-410-416}
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\elib{https://elibrary.ru/item.asp?id=35145928}
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  • https://www.mathnet.ru/eng/nano/v9/i3/p410
    • This publication is cited in the following 8 articles:
    1. M. E. Kurguzkina, T. P. Maslennikova, V. V. Gusarov, “Formirovanie, morfologiya i razmernye parametry nanoporoshkov na osnove nanosvitkov sostava Mg<sub>3</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>–Ni<sub>3</sub>Si<sub>2</sub>O<sub>5</sub>(OH)<sub>4</sub>”, Neorganicheskie materialy, 59:10 (2023), 1111  crossref
    2. M. E. Kurguzkina, T. P. Maslennikova, V. V. Gusarov, “Formation, Morphology, and Size Parameters of Nanopowders Based on Mg3Si2O5(OH)4–Ni3Si2O5(OH)4 Nanoscrolls”, Inorg Mater, 59:10 (2023), 1075  crossref
    3. E. K. Khrapova, D. A. Kozlov, A. A. Krasilin, “Hydrothermal Synthesis of Hydrosilicate Nanoscrolls (Mg1 – xCox)3Si2O5(OH)4 in a Na2SO3 Solution”, Russ. J. Inorg. Chem., 67:6 (2022), 839  crossref
    4. Ekaterina K. Khrapova, Valery L. Ugolkov, Elena A. Straumal, Sergey A. Lermontov, Vasily A. Lebedev, Daniil A. Kozlov, Tatyana S. Kunkel, Alexandre Nominé, Stephanie Bruyere, Jaafar Ghanbaja, Thierry Belmonte, Andrei A. Krasilin, “Thermal behavior of Mg-Ni‐phyllosilicate nanoscrolls and performance of the resulting composites in hexene‐1 and acetone hydrogenation”, ChemNanoMat, 7:3 (2021), 257  crossref
    5. Andrei A. Krasilin, Maksim M. Khalisov, Ekaterina K. Khrapova, Tatyana S. Kunkel, Daniil A. Kozlov, Nikolay M. Anuchin, Andrey N. Enyashin, Alexander V. Ankudinov, “Surface Tension and Shear Strain Contributions to the Mechanical Behavior of Individual Mg‐Ni‐Phyllosilicate Nanoscrolls”, Part & Part Syst Charact, 38:12 (2021)  crossref
    6. Andrei A. Krasilin, Ekaterina K. Khrapova, Alexandre Nominé, Jaafar Ghanbaja, Thierry Belmonte, Victor V. Gusarov, “Cation Redistribution along the Spiral of Ni‐Doped Phyllosilicate Nanoscrolls: Energy Modelling and STEM/EDS Study”, ChemPhysChem, 20:5 (2019), 719  crossref
    7. I.S. Bodalyov, A.A. Malkov, T.P. Maslennikova, A.A. Krasilin, A.A. Malygin, “Mechanism of formation of titanium dioxide crystallites in the reaction of titanium tetrachloride with magnesium hydrosilicate nanotubes”, Materials Today Chemistry, 11 (2019), 156  crossref
    8. Andrei A. Krasilin, Dmitry P. Danilovich, Elena B. Yudina, Stéphanie Bruyere, Jaafar Ghanbaja, Vladimir K. Ivanov, “Crystal violet adsorption by oppositely twisted heat-treated halloysite and pecoraite nanoscrolls”, Applied Clay Science, 173 (2019), 1  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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