N. B. Tamm, M. P. Kosaya, M. A. Fritz, S. I. Troyanov, “Synthesis, isolation, and X-ray structural characterization of trifluoromethylated $\mathrm{C}_{78}$ fullerenes: $\mathrm{C}_{78}(2)(\mathrm{CF}_3)_{10/12}$ and $\mathrm{C}_{78}(3)(\mathrm{CF}_3)_{12/14}$”, Nanosystems: Physics, Chemistry, Mathematics, 7:1 (2016), 111

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Nanosystems: Physics, Chemistry, Mathematics, 2016, Volume 7, Issue 1, Pages 111–117
DOI: https://doi.org/10.17586/2220-8054-2016-7-1-111-117 (Mi nano178)

This article is cited in 5 scientific papers (total in 5 papers)

PAPERS, PRESENTED AT THE CONFERENCE

Synthesis, isolation, and X-ray structural characterization of trifluoromethylated

C_{78}

$\mathrm{C}_{78}$ fullerenes:

C_{78} (2) ({C F}_{3})_{10 / 12}

$\mathrm{C}_{78}(2)(\mathrm{CF}_3)_{10/12}$ and

C_{78} (3) ({C F}_{3})_{12 / 14}

$\mathrm{C}_{78}(3)(\mathrm{CF}_3)_{12/14}$

N. B. Tamm, M. P. Kosaya, M. A. Fritz, S. I. Troyanov

Department of Chemistry, Moscow State University, Moscow, Russia

Full-text PDF (286 kB) Citations (5)

DOI: https://doi.org/10.17586/2220-8054-2016-7-1-111-117

Abstract: Four

{C F}_{3}

$\mathrm{CF}_3$ derivatives of

C_{78}

$\mathrm{C}_{78}$ ,

C_{78} (2) ({C F}_{3})_{10 / 12}

$\mathrm{C}_{78}(2)(\mathrm{CF}_3)_{10/12}$ and

C_{78} (3) ({C F}_{3})_{12 / 14}

$\mathrm{C}_{78}(3)(\mathrm{CF}_3)_{12/14}$ , have been isolated via HPLC from the products of high-temperature trifluoromethylation of a

C_{76}

$\mathrm{C}_{76}$ -

C_{96}

$\mathrm{C}_{96}$ fullerene mixture or a

C_{78}

$\mathrm{C}_{78}$ fraction. Their molecular structures were determined by single crystal X-ray crystallography using synchrotron radiation. The addition patterns of the new compounds are compared with each other and with the previously known C

C_{78} (2) ({C F}_{3})_{10}

$\mathrm{C}_{78}(2)(\mathrm{CF}_3)_{10}$ and

C_{78} (3) ({C F}_{3})_{12}

$\mathrm{C}_{78}(3)(\mathrm{CF}_3)_{12}$ .

Keywords: higher fullerenes,

C_{78}

$\mathrm{C}_{78}$ , trifluoromethylation, HPLC, structure elucidation.

Funding agency	Grant number
Russian Foundation for Basic Research	15-03-04464
This work was supported in part by the Russian Foundation for Basic Research (grant 15-03-04464).

Received: 20.11.2015

Bibliographic databases:

Document Type: Article

PACS: 61.48.-c

Language: English

Citation: N. B. Tamm, M. P. Kosaya, M. A. Fritz, S. I. Troyanov, “Synthesis, isolation, and X-ray structural characterization of trifluoromethylated

C_{78}

$\mathrm{C}_{78}$ fullerenes:

C_{78} (2) ({C F}_{3})_{10 / 12}

$\mathrm{C}_{78}(2)(\mathrm{CF}_3)_{10/12}$ and

C_{78} (3) ({C F}_{3})_{12 / 14}

$\mathrm{C}_{78}(3)(\mathrm{CF}_3)_{12/14}$ ”, Nanosystems: Physics, Chemistry, Mathematics, 7:1 (2016), 111–117

Citation in format AMSBIB

\Bibitem{TamKosFri16}

\by N.~B.~Tamm, M.~P.~Kosaya, M.~A.~Fritz, S.~I.~Troyanov

\paper Synthesis, isolation, and X-ray structural characterization of trifluoromethylated $\mathrm{C}_{78}$ fullerenes: $\mathrm{C}_{78}(2)(\mathrm{CF}_3)_{10/12}$ and $\mathrm{C}_{78}(3)(\mathrm{CF}_3)_{12/14}$

\jour Nanosystems: Physics, Chemistry, Mathematics

\yr 2016

\vol 7

\issue 1

\pages 111--117

\mathnet{http://mi.mathnet.ru/nano178}

\crossref{https://doi.org/10.17586/2220-8054-2016-7-1-111-117}

\isi{https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Publons&SrcAuth=Publons_CEL&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=000387461500016}

Linking options:

https://www.mathnet.ru/eng/nano178

https://www.mathnet.ru/eng/nano/v7/i1/p111

This publication is cited in the following 5 articles:

Victor A. Brotsman, Daria V. Ignat'eva, Sergey I. Troyanov, “Chlorination‐promoted Transformation of Isolated Pentagon Rule C78 into Fused‐pentagons‐ and Heptagons‐containing Fullerenes”, Chemistry — An Asian Journal, 12:18 (2017), 2379
Fei Jin, Song Wang, Nadezhda B. Tamm, Shangfeng Yang, Sergey I. Troyanov, “Synthesis, Isolation, and Trifluoromethylation of Two Isomers of C84‐Based Monometallic Cyanide Clusterfullerenes: Interplay between the Endohedral Cluster and the Exohedral Addends”, Angew Chem Int Ed, 56:39 (2017), 11990
Fei Jin, Song Wang, Nadezhda B. Tamm, Shangfeng Yang, Sergey I. Troyanov, “Synthesis, Isolation, and Trifluoromethylation of Two Isomers of C84‐Based Monometallic Cyanide Clusterfullerenes: Interplay between the Endohedral Cluster and the Exohedral Addends”, Angewandte Chemie, 129:39 (2017), 12152
Song Wang, Shangfeng Yang, Erhard Kemnitz, Sergey I. Troyanov, “New Giant Fullerenes Identified as Chloro Derivatives: Isolated-Pentagon-Rule C108(1771)Cl12 and C106(1155)Cl24 as well as Nonclassical C104Cl24”, Inorg. Chem., 55:12 (2016), 5741
Maria P. Kosaya, Maria A. Fritz, Victor A. Brotsman, Nadezhda B. Tamm, Daria V. Ignat'eva, Sergey I. Troyanov, “Synthesis, Isolation and Structure of Trifluoromethylated Fullerene D3‐C78, C78(1)(CF3)10-18”, Chemistry — An Asian Journal, 11:7 (2016), 1000

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

Nanosystems: Physics, Chemistry, Mathematics

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