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CHEMISTRY AND MATERIAL SCIENCE
Ultrasonic-assisted hydrothermal synthesis of nanoscale double ceric phosphates
Taisiya O. Kozlovaa, Ekaterina D. Sheichenkoab, Darya N. Vasilyevaab, Daniil A. Kozlova, Irina V. Kolesnikac, Ilya V. Tronevab, Maria A. Teplonogovaa, Alexander Y. Baranchikova, Vladimir K. Ivanova a Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow, Russia
b National Research University Higher School of Economics, Moscow, Russia
c Lomonosov Moscow State University, Moscow, Russia
Abstract:
The combination of ultrasonic exposure on ceric phosphate gels with subsequent hydrothermalmicrowave treatment resulted in the formation of nanoscale NH$_4$Ce$_2$(PO$_4$)$_3$ or KCe$_2$(PO$_4$)$_3$ phases. The sun protection factor (SPF) and protection factor against UV-A radiation (UVAPF) values for double ceric phosphates with the smallest crystallite sizes exceeded 4 and 3.5, respectively, which is much higher than the values for samples consisting of larger particles. These results are superior to previously published values for similar ceric compounds, and thus show promise for their application in sunscreens.
Keywords:
cerium, ultrasonic exposure, microwave, particle size, UV shielding.
Received: 30.01.2024 Revised: 10.02.2024 Accepted: 31.03.2024
Citation:
Taisiya O. Kozlova, Ekaterina D. Sheichenko, Darya N. Vasilyeva, Daniil A. Kozlov, Irina V. Kolesnik, Ilya V. Tronev, Maria A. Teplonogova, Alexander Y. Baranchikov, Vladimir K. Ivanov, “Ultrasonic-assisted hydrothermal synthesis of nanoscale double ceric phosphates”, Nanosystems: Physics, Chemistry, Mathematics, 15:2 (2024), 215–223
Linking options:
https://www.mathnet.ru/eng/nano1264 https://www.mathnet.ru/eng/nano/v15/i2/p215
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