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Nanosystems: Physics, Chemistry, Mathematics, 2018, Volume 9, Issue 1, Pages 29–32
DOI: https://doi.org/10.17586/2220-8054-2018-9-1-29-32 (Mi nano116) 		 
FROM GUEST EDITORIAL

Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers

K. P. Meletova, J. Arvanitidisb, D. Christofilosb, G. Kourouklisb, V. A. Davydovc

a Institute of Solid State Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow region, Russia
b Aristotle University of Thessaloniki, GR54124 Thessaloniki, Greece
c Institute of High Pressure Physics, Russian Academy of Sciences, 42092 Troitsk, Moscow region, Russia
Full-text PDF (2327 kB)
DOI: https://doi.org/10.17586/2220-8054-2018-9-1-29-32
Abstract: The decomposition kinetics of the fullerene dimers and photo-oligomers was studied at elevated temperature by Raman scattering. The polymeric content decreases exponentially with the thermal treatment time while the decay time constant decreases at higher temperatures. The activation-type behavior is well described by the Arrhenius law that gives the activation energy E$_A$ = (1.71 $\pm$ 0.06) eV/molecule for the dimers and E$_A$ = (0.87 $\pm$ 0.06) eV/molecule for the C$_{60}$ photopolymer.
Keywords: fullerene polymers, Raman spectroscopy, decomposition kinetics.
Funding agency Grant number
Russian Foundation for Basic Research 15-02-01495
Russian Academy of Sciences - Federal Agency for Scientific Organizations
K.P.M. acknowledges the main financial support by the Federal Agency for Scientific Organizations, the partial support by the Russian Foundation for Fundamental Research, grant 15-02-01495, the RAS Presidium Program “Physics of compressed matter”, as well as the hospitality of the Aristotle University of Thessaloniki.
Received: 14.06.2017
Revised: 22.09.2017
Bibliographic databases:
Document Type: Article
PACS: 78.30.Na
Language: English
Citation: K. P. Meletov, J. Arvanitidis, D. Christofilos, G. Kourouklis, V. A. Davydov, “Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers”, Nanosystems: Physics, Chemistry, Mathematics, 9:1 (2018), 29–32
Citation in format AMSBIB
\Bibitem{MelArvChr18}
\by K.~P.~Meletov, J.~Arvanitidis, D.~Christofilos, G.~Kourouklis, V.~A.~Davydov
\paper Stability at high temperature and decomposition kinetics of the fullerene dimers and photopolymers
\jour Nanosystems: Physics, Chemistry, Mathematics
\yr 2018
\vol 9
\issue 1
\pages 29--32
\mathnet{http://mi.mathnet.ru/nano116}
\crossref{https://doi.org/10.17586/2220-8054-2018-9-1-29-32}
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\elib{https://elibrary.ru/item.asp?id=32538117}
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