Abstract:
The effect of nickel content in Mg1−xNix(OH)2 nanoparticles produced by reverse co-precipitation on their structural characteristics, morphology and size parameters of crystallites and particles has been studied. The plate-shaped nanoparticles were shown to be predominantly single crystals. It has been determined that when the nickel content x in the hydroxide solid solution is not less than 0.4, the particle size sharply decreases and the number of stacking faults increases. The dependence of the dehydration temperature of Mg1−xNix(OH)2 nanoparticles on the nickel content has been revealed.
TEM was done by D. A. Kirilenko (Ioffe Institute) using the equipment of the Federal Collective Use Center “Materials Science and Diagnostics in Advanced Technologies” supported by the Ministry of Education and Science of Russia (Project Unique ID RFMEFI62117X0018). The work was carried out in the framework of the State Assignment to the Institute of Silicate Chemistry of RAS with support from the Ministry of Education and Science of Russia (Topic
№ 0081-2022-0008).
Citation:
Maria E. Kotova, Tatiana P. Maslennikova, Valery L. Ugolkov, Victor V. Gusarov, “Formation, structure, composition in the dispersed state, and behavior of nanoparticles heated in the Mg(OH)2 – Ni(OH)2 system”, Nanosystems: Physics, Chemistry, Mathematics, 13:5 (2022), 514–524