Abstract:
A model describing the interaction of hydrated ions in the electrolyte was proposed. The developed approach allows us to calculate the action of the main physical factors, and explain the nature of the curves describing the activity coefficients on this basis. The results of simulation are tested on a large number of experimental data.
Keywords:
activity coefficients, statistical approach, electrostatic potential, energy of the hydrate shell.
Citation:
N. A. Tikhonov, G. B. Sidelnikov, “Modeling of physical effects, determining the change in the activity coefficients of electrolytes”, Mat. Model., 26:6 (2014), 17–26; Math. Models Comput. Simul., 7:1 (2015), 6–12
\Bibitem{TikSid14}
\by N.~A.~Tikhonov, G.~B.~Sidelnikov
\paper Modeling of physical effects, determining the change in the activity coefficients of electrolytes
\jour Mat. Model.
\yr 2014
\vol 26
\issue 6
\pages 17--26
\mathnet{http://mi.mathnet.ru/mm3486}
\transl
\jour Math. Models Comput. Simul.
\yr 2015
\vol 7
\issue 1
\pages 6--12
\crossref{https://doi.org/10.1134/S207004821501010X}
\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-84925965640}
Linking options:
https://www.mathnet.ru/eng/mm3486
https://www.mathnet.ru/eng/mm/v26/i6/p17
This publication is cited in the following 2 articles:
R. Kh. Khamizov, A. N. Krachak, N. S. Vlasovskikh, A. N. Gruzdeva, Advances in Geochemistry, Analytical Chemistry, and Planetary Sciences, 2023, 499
Khamizov R.Kh. Tikhonov N.A. Krachak A.N. Gruzdeva A.N. Vlasovskikh N.S., “Separation of Concentrated Acid and Salt Solutions in Nanoporous Media as the Basis For a New Technology of Processing of Phosphorus-Containing Raw Materials”, Geochem. Int., 54:13 (2016), 1221–1235
Citation in format AMSBIB
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