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Mendeleev Communications, 2021, Volume 31, Issue 5, Pages 584–592
DOI: https://doi.org/10.1016/j.mencom.2021.09.002
(Mi mendc995)
 

This article is cited in 32 scientific papers (total in 32 papers)

Focus Article

Challenges for the utilization of methane as a chemical feedstock

R. Franza, E. Uslaminab, E. A. Pidkoa

a Chemical Engineering Department, Delft University of Technology, HZ Delft, The Netherlands
b TsyfroCatLab Group, University of Tyumen, Tyumen, Russian Federation
Abstract: The abundance of methane has led to a strong interest to use methane as a feedstock in the chemical industry. One of the main challenges is the initial activation of the methane molecule. This has resulted in the development of several different approaches to utilize methane, some more developed than others. In this work the current status of the different approaches is discussed and the main issues for industrial utilization described. A special focus of this work is the status of catalyst development.
Keywords: Methane activation, Heterogeneous catalysis, Methane upgrading, Catalysis engineering, Catalyst deactivation, Steam reforming, Dry reforming, Selective oxidation, Methane halogenation, Methanol.
Document Type: Article
Language: English


Citation: R. Franz, E. Uslamin, E. A. Pidko, “Challenges for the utilization of methane as a chemical feedstock”, Mendeleev Commun., 31:5 (2021), 584–592
Linking options:
  • https://www.mathnet.ru/eng/mendc995
  • https://www.mathnet.ru/eng/mendc/v31/i5/p584
  • This publication is cited in the following 32 articles:
    1. Cholila Tamzysi, Tatsuya Takahashi, Yuji Kunisada, Ade Kurniawan, Takahiro Nomura, “Optimizing Ni MEPCM catalysts for thermal regulation in CO2 methanation: ZrO2-CaO surface doping”, Chemical Engineering Journal, 2025, 159753  crossref
    2. Jianzhi Bai, Xue Liang, Hui Hwang Goh, Tonni Agustiono Kurniawan, Kai Chen Goh, Xifeng Xie, Yi Peng, Lingyun Liu, Jianghong Yin, “Promoting decarbonization in waste and energy sectors in Delhi (India) through circular economy and resource recovery: A low carbon transition towards renewable energy”, Energy Reports, 13 (2025), 2106  crossref
    3. Jedy Prameswari, Yu-Chuan Lin, “Innovative Catalysis Approaches for Methane Utilization”, ACS EST Eng., 2025  crossref
    4. Pawan Kumar, Peter Antal, Xiyang Wang, Jiu Wang, Dhwanil Trivedi, Ondřej František Fellner, Yimin A. Wu, Ivan Nemec, Vinicius Tadeu Santana, Josef Kopp, Petr Neugebauer, Jinguang Hu, Md Golam Kibria, Subodh Kumar, “Partial Thermal Condensation Mediated Synthesis of High‐Density Nickel Single Atom Sites on Carbon Nitride for Selective Photooxidation of Methane into Methanol”, Small, 20:15 (2024)  crossref
    5. Leah R. Filardi, Fernando D. Vila, Jiyun Hong, Adam S. Hoffman, Jorge E. Perez-Aguilar, Simon R. Bare, Ron C. Runnebaum, Coleman X. Kronawitter, “Impact of Local Structure in Supported CaO Catalysts for Soft-Oxidant-Assisted Methane Coupling Assessed through Ca K-Edge X-ray Absorption Spectroscopy”, J. Phys. Chem. C, 128:3 (2024), 1165  crossref
    6. Anton A. Gabrienko, Ekaterina S. Kvasova, Daniil I. Kolokolov, Dmitry E. Gorbunov, Anton S. Nizovtsev, Zoya N. Lashchinskaya, Alexander G. Stepanov, “Understanding Alkene Interaction with Metal-Modified Zeolites: Thermodynamics and Mechanism of Bonding in the π-Complex”, Inorg. Chem., 63:11 (2024), 5083  crossref
    7. Sirisha Subbareddy, Santhosh Arehalli Shivamurthy, Srujan Basavapura Ravikumar, Hema Mylnahalli Krishnegowda, Sandeep Shadakshari, Manickam Selvaraj, Sanjay Basumatary, “Structural crystal engineering for energy: Unleashing the potential of metal-organic frameworks for photocatalytic reduction of carbon dioxide”, Materials Today Chemistry, 40 (2024), 102197  crossref
    8. Haoran Ding, Shenghui Liu, Fei Liu, Long Han, Shien Sun, Zhifu Qi, “Experimental and numerical investigation of chemical-loop steam methane reforming on monolithic BaCoO3/CeO2 oxygen”, Energy, 302 (2024), 131896  crossref
    9. Dongmiao Li, Min Lin, Jiangjie Zhang, Chengwei Qiu, Hui Chen, Zhen Xiao, Jinni Shen, Yuanhui Zheng, Jinlin Long, Wenxin Dai, Xuxu Wang, Xianzhi Fu, Zizhong Zhang, “Hydrophobic TaOx Species Overlayer Tuning Light‐Driven Methane Chlorination with Inorganic Chlorine”, Small, 2024  crossref
    10. Liza Ainalen Dosso, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2024  crossref
    11. Peaush Gangwar, C.N. Ramachandran, “Conversion of the greenhouse gases CH4 and CO2 to CH3COOH using transition metal Clusters: Two birds with one stone”, Chemical Physics Letters, 846 (2024), 141339  crossref
    12. Mohammadali Nasrabadi, Agus Dwi Anggono, Lidia Sergeevna Budovich, Sherzod Abdullaev, Serikzhan Opakhai, “Optimizing membrane reactor structures for enhanced hydrogen yield in CH4 tri-reforming: Insights from sensitivity analysis and machine learning approaches”, International Journal of Thermofluids, 22 (2024), 100690  crossref
    13. Shuya Hao, Yangshen Chen, Chen Peng, Huining Wang, Qianyou Wen, Cejun Hu, Lijuan Zhang, Qing Han, Gengfeng Zheng, “Photocatalytic Coupling of CH4 and CO2 to Ethanol on Asymmetric Ce-O-Zn Sites”, Adv Funct Materials, 34:17 (2024)  crossref
    14. Xianyao Yan, Chenyu Duan, Shuihua Yu, Bing Dai, Chaoying Sun, Huaqiang Chu, “Recent advances on CO2 reduction reactions using single-atom catalysts”, Renewable and Sustainable Energy Reviews, 190 (2024), 114086  crossref
    15. Mackenzie Meyer, Sanjana Kerketta, Ryan Hartman, Mark J. Kushner, “CH3 Radical Generation in Microplasmas for Up-Conversion of Methane”, J. Phys. Chem. A, 128:13 (2024), 2656  crossref
    16. Sven Schardt, Simon Bastian, Ahmet Çelik, Jaspreet Chawla, Patrick Lott, “Influence of Dopants on Pt/Al2O3-Based Monolithic Catalysts for Autothermal Oxidative Coupling of Methane”, Catalysts, 14:11 (2024), 785  crossref
    17. Hyo Jin Hong, Ji Sung Hyung, Jinwon Lee, Jeong-Geol Na, “Effects of methane to oxygen ratio on cell growth and polyhydroxybutyrate synthesis in high cell density cultivation of Methylocystis sp. MJC1”, Environ Sci Pollut Res, 2024  crossref
    18. Jin Liu, Yao Wei, Ruitao Li, Yuxin Liu, Hailing Yu, Xuan Zhou, Bo Wu, Tiejun Lin, Liangshu Zhong, “Isolated Ni sites anchored on zeolites for direct synthesis of acetic acid from methane oxidative carbonylation”, Applied Catalysis B: Environment and Energy, 350 (2024), 123951  crossref
    19. Caihong Weng, Xiaowei Peng, Yejun Han, Advances in Applied Microbiology, 124, 2023, 119  crossref
    20. Jaime S. Valente, Roberto Quintana-Solórzano, Héctor Armendáriz-Herrera, Jean-Marc M. Millet, “Decarbonizing Petrochemical Processes: Contribution and Perspectives of the Selective Oxidation of C1–C3 Paraffins”, ACS Catal., 13:3 (2023), 1693  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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