Abstract:
An efficient and practical method for a scalable synthesis of 3-arylbutadiene sulfones deals with the ligand-free Heck–Matsuda reaction of sulfolene with aryldiazonium tetrafluoroborates followed by triethylamine-promoted double bond shift.
Citation:
S. A. Rzhevskiy, V. N. Bogachev, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, M. A. Topchiy, A. F. Asachenko, “Efficient synthesis of 3-arylbutadiene sulfones using the Heck–Matsuda reaction”, Mendeleev Commun., 31:4 (2021), 548–549
Linking options:
https://www.mathnet.ru/eng/mendc985
https://www.mathnet.ru/eng/mendc/v31/i4/p548
This publication is cited in the following 3 articles:
Olga V. Shurupova, Sergey A. Rzhevskiy, Lidiya I. Minaeva, Maxim A. Topchiy, Andrey F. Asachenko, “Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction”, RSC Adv., 12:9 (2022), 5517
M. A. Topchiy, A. N. Lysenko, M. A. Rasskazova, A. A. Ageshina, S. A. Rzhevskiy, L. I. Minaeva, M. S. Nechaev, A. F. Asachenko, “Arylation of nitromethane with sterically hindered aryl halides”, Russ Chem Bull, 71:1 (2022), 59
O. V. Shurupova, G. K. Sterligov, M. A. Rasskazova, E. A. Drokin, A. N. Lysenko, S. A. Rzhevskiy, L. I. Minaeva, M. A. Topchiy, A. F. Asachenko, “One-pot two step synthesis of unsymmetrically substituted indenes from 3,4-diarylbutadiene sulfones”, Mendeleev Commun., 32:4 (2022), 446–448
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