Abstract:
Screening of four Buchwald ligands for the cross-coupling of isomeric di-, tri- and tetrachlorobenzenes with arylboronic acids revealed that good yields of exhaustive substitution can be best provided by 2-dicyclohexylphosphino-2′-(dimethylamino) biphenyl (DavePHOS).
Citation:
A. A. Vasil'ev, A. S. Burukin, G. M. Zhdankina, S. G. Zlotin, “Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes”, Mendeleev Commun., 31:3 (2021), 400–402
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https://www.mathnet.ru/eng/mendc943
https://www.mathnet.ru/eng/mendc/v31/i3/p400
This publication is cited in the following 7 articles:
A. A. Vasil'ev, A. A. Burukin, G. M. Zhdankina, S. G. Zlotin, “Catalytic amination of polychloroarenes promoted by the Buchwald ligands”, Russ Chem Bull, 72:11 (2023), 2749
T. I. Gorbunova, N. S. Kozhevnikova, A. N. Enyashin, “The lifetime of polychlorophenyl radicals in methanol: A SCC–DFTB molecular dynamics study”, Mendeleev Commun., 33:5 (2023), 661–665
M. A. Topchiy, A. N. Lysenko, M. A. Rasskazova, A. A. Ageshina, S. A. Rzhevskiy, L. I. Minaeva, M. S. Nechaev, A. F. Asachenko, “Arylation of nitromethane with sterically hindered aryl halides”, Russ Chem Bull, 71:1 (2022), 59
A. A. Vasil'ev, A. S. Burukin, G. M. Zhdankina, S. G. Zlotin, “Suzuki cross-coupling of hexachlorobenzene promoted by the Buchwald ligands”, Russ Chem Bull, 71:1 (2022), 169
A. A. Vasil'ev, A. S. Burukin, G. M. Zhdankina, S. G. Zlotin, “Functionalized polychloroarenes in the Bichwald ligand-promoted Suzuki cross-coupling”, Russ Chem Bull, 71:8 (2022), 1656
L. A. Bulygina, N. S. Khrushcheva, K. A. Lyssenko, A. S. Peregudov, “Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction”, Mendeleev Commun., 32:3 (2022), 331–333
V. A. Egorov, L. S. Khasanova, F. A. Gimalova, A. N. Lobov, D. V. Ishmetova, V. A. Vakhitov, M. S. Miftakhov, “Cytotoxicity of novel cross-conjugated arylated cyclopentene-1,3-diones”, Mendeleev Commun., 32:2 (2022), 183–185
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