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Mendeleev Communications, 2021, Volume 31, Issue 2, Pages 277–279
DOI: https://doi.org/10.1016/j.mencom.2021.03.045
(Mi mendc905)
 

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Polymerization-induced phase separation in gradient copolymers

M. Yu. Zaremskia, E. Yu. Kozhunovab, S. S. Abramchukb, M. E. Glavatskayaa, A. V. Chertovichbc

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Department of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Gradient copolymers of styrene and N-vinylpyrrolidone, obtained in bulk using the reversible deactivation radical polymerization process under the action of TEMPO nitroxide, can form microphase-like separated structures directly in the reaction medium without any additional treatment or solvent. The morphology of the resulting product is highly dependent on the monomer feed composition.
Keywords: microphase separation, gradient copolymers, block copolymers, polymerization-induced self-assembly, nitroxide.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (307.8 Kb)


Citation: M. Yu. Zaremski, E. Yu. Kozhunova, S. S. Abramchuk, M. E. Glavatskaya, A. V. Chertovich, “Polymerization-induced phase separation in gradient copolymers”, Mendeleev Commun., 31:2 (2021), 277–279
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  • https://www.mathnet.ru/eng/mendc905
  • https://www.mathnet.ru/eng/mendc/v31/i2/p277
  • This publication is cited in the following 7 articles:
    1. V. S. Kravchenko, R. A. Gumerov, I. I. Potemkin, “Recent Advances in Diblock and Gradient Copolymers Self-Assembly in Solutions and at the Interfaces”, rev. and adv. in chem., 2025  crossref
    2. Laura García Andújar, Anne-Laure Brocas, Sylvain Bourrigaud, Sylvie Cazaumayou, Christophe Derail, Maud Save, Laurent Rubatat, “Controlled Asymmetric Lamellar Nanomorphology Obtained through Nitroxide-Mediated Polymerization-Induced Microphase Separation”, Macromolecules, 57:7 (2024), 3090  crossref
    3. Natalia S. Serkhacheva, Nickolay I. Prokopov, Evgenii A. Lysenko, Elena Yu. Kozhunova, Elena V. Chernikova, “Modern Trends in Polymerization-Induced Self-Assembly”, Polymers, 16:10 (2024), 1408  crossref
    4. Arielle L. Santefort, Alayna C. Appolon, Luke J. Cowart, Devon A. Shipp, “Surface Eroding Methacrylic Anhydride Copolymers and Model Drug Release”, Macro Chemistry & Physics, 224:18 (2023)  crossref
    5. Arielle L. Santefort, Philip A. Yuya, Devon A. Shipp, “Dynamic covalent exchange in methacrylic anhydride copolymers”, Polymer, 281 (2023), 126120  crossref
    6. Elena Kozhunova, Anna Plutalova, Elena Chernikova, “RAFT Copolymerization of Vinyl Acetate and Acrylic Acid in the Selective Solvent”, Polymers, 14:3 (2022), 555  crossref
    7. E. V. Chernikova, K. O. Mineeva, “Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit Sequence”, Polym. Sci. Ser. C, 64:1 (2022), 1  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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