Abstract:
Gradient copolymers of styrene and N-vinylpyrrolidone, obtained in bulk using the reversible deactivation radical polymerization process under the action of TEMPO nitroxide, can form microphase-like separated structures directly in the reaction medium without any additional treatment or solvent. The morphology of the resulting product is highly dependent on the monomer feed composition.
Citation:
M. Yu. Zaremski, E. Yu. Kozhunova, S. S. Abramchuk, M. E. Glavatskaya, A. V. Chertovich, “Polymerization-induced phase separation in gradient copolymers”, Mendeleev Commun., 31:2 (2021), 277–279
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https://www.mathnet.ru/eng/mendc/v31/i2/p277
This publication is cited in the following 7 articles:
V. S. Kravchenko, R. A. Gumerov, I. I. Potemkin, “Recent Advances in Diblock and Gradient Copolymers Self-Assembly in Solutions and at the Interfaces”, rev. and adv. in chem., 2025
Natalia S. Serkhacheva, Nickolay I. Prokopov, Evgenii A. Lysenko, Elena Yu. Kozhunova, Elena V. Chernikova, “Modern Trends in Polymerization-Induced Self-Assembly”, Polymers, 16:10 (2024), 1408
Arielle L. Santefort, Alayna C. Appolon, Luke J. Cowart, Devon A. Shipp, “Surface Eroding Methacrylic Anhydride Copolymers and Model Drug Release”, Macro Chemistry & Physics, 224:18 (2023)
Arielle L. Santefort, Philip A. Yuya, Devon A. Shipp, “Dynamic covalent exchange in methacrylic anhydride copolymers”, Polymer, 281 (2023), 126120
Elena Kozhunova, Anna Plutalova, Elena Chernikova, “RAFT Copolymerization of Vinyl Acetate and Acrylic Acid in the Selective Solvent”, Polymers, 14:3 (2022), 555
E. V. Chernikova, K. O. Mineeva, “Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit Sequence”, Polym. Sci. Ser. C, 64:1 (2022), 1