aSchool of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China bSchool of Petrochemical Engineering, Changzhou University, Changzhou, China
Abstract:
Nickel-catalyzed reduction of (het)arenecarboxylic acids with hydrosilanes in the presence of dimethyl dicarbonate as the activator affords the corresponding aldehydes. The role of the activator is the conversion of the acids into their anhydrides undergoing C–O cleavage. The good yields were achieved in case of substrates bearing electron-donating and electron-neutral groups.
Citation:
L. Wang, Ya. Wang, Yu. Tao, N. Zhang, Sh. Li, “Nickel catalyzed hydrosilane reduction of (het)arenecarboxylic acids into aldehydes”, Mendeleev Commun., 31:2 (2021), 271–273
Linking options:
https://www.mathnet.ru/eng/mendc903
https://www.mathnet.ru/eng/mendc/v31/i2/p271
This publication is cited in the following 3 articles:
Vladimir V. Zotov, Carl Zupancic, Zachary J. Bailey, Guodong Du, “Ring Opening Reduction of Cyclic Anhydrides Catalyzed by Tris(pentafluorophenyl)borane Using Hydrosilanes as a Hydride Source”, J. Org. Chem., 89:21 (2024), 15436
Zhiwen Nie, Tonglin Yang, Miaodong Su, Weiping Luo, Qiang Liu, Cancheng Guo, “One‐Step Synthesis of Arylacetaldehydes from Aryl Aldehydes or Diaryl Ketones via One‐Carbon Extension by Using the System of DMSO/KOH/Zinc”, Adv Synth Catal, 364:17 (2022), 2989
Zhanhui Yang, “Partial reductions of carboxylic acids and their derivatives to aldehydes”, Org. Chem. Front., 9:14 (2022), 3908
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