Abstract:
Palladium complexes with N-heterocyclic carbene ligands of a new type containing free NH2 group were obtained by direct palladation of 3-amino-1,4-dialkyl-1,2,4-triazolium salts. These amino-functionalized complexes were found to be a versatile platform for postmodification via reactions of the NH2 group with acyl and sulfonyl chlorides.
Citation:
D. V. Pasyukov, A. Yu. Chernenko, K. E. Shepelenko, V. V. Kutyrev, V. N. Khrustalev, V. M. Chernyshev, “3-Amino-1,2,4-triazolium salts as NHC-proligands: synthesis and postmodification of a new type of amino-functionalized Pd/NHC complexes”, Mendeleev Commun., 31:2 (2021), 176–178
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https://www.mathnet.ru/eng/mendc870
https://www.mathnet.ru/eng/mendc/v31/i2/p176
This publication is cited in the following 10 articles:
M. A. Shevchenko, D. V. Pasyukov, I. V. Lavrentiev, M. E. Minyaev, V. M. Chernyshev, “Synthesis of 4-amino-1,3-diarylimidazolium chlorides”, Doklady Rossijskoj akademii nauk. Himiâ, nauki o materialah., 515:1 (2024)
Andrey Yu. Chernenko, Victoria A. Baydikova, Vadim V. Kutyrev, Alexander V. Astakhov, Mikhail E. Minyaev, Victor M. Chernyshev, Valentine P. Ananikov, “Base‐Ionizable Anionic NHC Ligands in Pd‐catalyzed Reactions of Aryl Chlorides”, ChemCatChem, 16:5 (2024)
A. Yu. Chernenko, V. A. Baydikova, M. E. Minyaev, V. M. Chernyshev, “Nitron analogs containing an N-arylcarbamoylmethyl group and Pd complexes derived therefrom: synthesis and catalytic activity in the Suzuki—Miyaura reaction”, Russ Chem Bull, 73:4 (2024), 932
A. Yu. Chernenko, K. E. Shepelenko, M. E. Minyaev, V. M. Chernyshev, “Novel ruthenium(ii) complexes with chelating 1,2,4-triazole NHC ligands and their catalytic activity in the transfer hydrogenation of ketones”, Mendeleev Commun., 34:3 (2024), 385–388
A. S. Pyatachenko, A. Yu. Chernenko, S. B. Soliev, M. E. Minyaev, V. M. Chernyshev, “Nickel(ii) complexes with novel nitron-type NHC ligands: synthesis and catalytic activity in the Suzuki–Miyaura coupling of aryl chlorides”, Mendeleev Commun., 34:1 (2024), 39–42
Jia Song, Juan Zou, Jiamiao Jin, Jie Lv, Chengli Mou, Yonggui Robin Chi, “Bioactivities of Triazolium‐Based N‐Heterocyclic Carbene Salts”, Chemistry A European J, 29:31 (2023)
M. A. Shevchenko, D. V. Pasyukov, Yu. N. Tkachenko, M. E. Minyaev, V. M. Chernyshev, “Synthesis of dicationic hetarylmethylimidazolium salts via the reaction of N, N′-diaryl-4-chloromethylimidazolium chlorides with N-heterocycles”, Russ Chem Bull, 72:5 (2023), 1225
D. V. Pasyukov, A. Yu. Chernenko, I. V. Lavrentev, V. A. Baydikova, M. E. Minyaev, O. A. Starovoytova, V. M. Chernyshev, “Dimroth rearrangement “thiadiazole-triazole”: synthesis and exploration of 3-sulfanyl-1,2,4-triazolium salts as NHC-proligands”, Russ Chem Bull, 71:5 (2022), 993
A. Yu. Chernenko, V. A. Baydikova, A. V. Astakhov, M. E. Minyaev, V. M. Chernyshev, “Nickel-Catalyzed N-Arylation of C-Amino-1,2,4-triazoles with Arylboronic Acids”, Dokl Chem, 504:2 (2022), 93
G. T. Sukhanov, Yu. V. Filippova, Yu. V. Gatilov, A. G. Sukhanova, K. K. Bosov, I. A. Krupnova, E. V. Pivovarova, “Acidic N-dealkylation in nitrotriazolium salts”, Mendeleev Commun., 32:2 (2022), 215–217
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