Abstract:
We demonstrate that a widely used inorganic holetransporting material, copper iodide (CuI), gets dissolved if halide perovskites are deposited atop from solutions which compromises the fabrication of CuI/perovskite heterojunctions using these methods. On the contrary, solvent-free approaches allow for the retaining of the CuI layer under the halide perovskite film thus making this approach beneficial for the development of perovskite photovoltaics.
Citation:
A. Yu. Grishko, E. A. Zharenova, E. A. Goodilin, A. B. Tarasov, “Solvent-free deposition of hybrid halide perovskites onto thin films of copper iodide p-type conductor”, Mendeleev Commun., 31:2 (2021), 163–165
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https://www.mathnet.ru/eng/mendc/v31/i2/p163
This publication is cited in the following 11 articles:
Aleksei Iu. Grishko, Aleksandra A. Shneiderman, Eugene G. Maksimov, Andrei A. Eliseev, “Enabling defect control or polyiodide formation regimes in halide perovskites”, Materials Chemistry and Physics, 329 (2025), 129978
I. A. Shentseva, A. N. Usoltsev, N. A. Korobeynikov, I. V. Korolkov, M. N. Sokolov, S. A. Adonin, “Structures and Properties of Polymeric Iodobismuthates Cat{[BiI4]} with Pyridinium-Derived Cations”, Russ. J. Inorg. Chem., 2024
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin, “Iodine-Rich Supramolecular Complexes of Chlorobismuthates(III): Unusual Lone Pair Activity and Features of Halogen Bonding in Crystals”, Inorg. Chem., 63:38 (2024), 17755
I. A. Shentseva, A. U. Usoltsev, N. A. Korobeynikov, I. V. Korolkov, M. N. Sokolov, S. A. Adonin, “Polymeric iodobismuthates Cat{[BiI4]} with pyridinium-derived cations: structure and properties”, Žurnal neorganičeskoj himii, 69:7 (2024), 999
Emily Smith, D. Venkataraman, “Deleterious Effects of Halides and Solvents used in Electronic Device Fabrication on the Integrity of Copper Iodide Thin‐Films**”, ChemPlusChem, 87:8 (2022)
Nikita A. Korobeynikov, Andrey N. Usoltsev, Pavel A. Abramov, Maxim N. Sokolov, Sergey A. Adonin, “Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors”, Molecules, 27:12 (2022), 3859
N. A. Korobeynikov, A. N. Usoltsev, M. N. Sokolov, S. A. Adonin, “Iodobismuthate(iii) complex with coordinated triiodide ligand and 3D supramolecular structure”, Mendeleev Commun., 32:6 (2022), 786–788
S. S. Kozlov, A. B. Nikolskaia, O. V. Alexeeva, E. K. Kosareva, O. V. Almjasheva, V. V. Gusarov, O. I. Shevaleevskiy, L. L. Larina, “Bismuth iron tungstate pyrochlore thin films for photovoltaic applications”, Mendeleev Commun., 32:6 (2022), 757–758
N. A. Korobeynikov, A. N. Usoltsev, T. S. Sukhikh, V. R. Shayapov, M. N. Sokolov, S. A. Adonin, “Isostructural hybrid iodometalate(III)/triiodide salts with perovskite-like packing: comparison of physical properties for SbIII and BiIII complexes”, Mendeleev Commun., 32:4 (2022), 517–519
I. A. Shentseva, A. N. Usoltsev, P. A. Abramov, V. R. Shayapov, N. A. Korobeynikov, M. N. Sokolov, S. A. Adonin, “Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties”, Mendeleev Commun., 32:6 (2022), 754–756
Sergey A. Fateev, Aleksandra S. Shatilova, Eugene A. Goodilin, Alexey B. Tarasov, “New Methylamine-Iodine-Mediated Solvent-Free Approach of Hybrid Perovskite Synthesis via the Redox Conversion of Metallic Lead Films”, ACS Omega, 6:31 (2021), 20249
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