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Mendeleev Communications, 2021, Volume 31, Issue 1, Pages 130–131
DOI: https://doi.org/10.1016/j.mencom.2021.01.042 (Mi mendc858) 		 
This article is cited in 2 scientific papers (total in 2 papers)

Communications

Synthesis of B-silylmethyl substituted o- and m-carboranes

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (173 kB) Citations (2)
DOI: https://doi.org/10.1016/j.mencom.2021.01.042
Abstract: Monosubstituted B-chloro(organyl)silylmethyl-o- and m-carboranes have been synthesized by the reaction of o(m)-carboranes with chloro(chloromethyl)organylsilanes in the presence of AlCl3 at 200–250°C under a pressure of 20–25atm.
Keywords: o(m)-carborane, chloro(chloromethyl)organylsilanes, B-chloro(organo)silyl-o(m)-carboranes, Fridel–Crafts reaction, organosilicon compounds.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (222.4 Kb)


Citation: B. A. Izmaylov, V. A. Vasnev, G. D. Markova, “Synthesis of B-silylmethyl substituted o- and m-carboranes”, Mendeleev Commun., 31:1 (2021), 130–131
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  • https://www.mathnet.ru/eng/mendc858
  • https://www.mathnet.ru/eng/mendc/v31/i1/p130
    • This publication is cited in the following 2 articles:
    1. E. O. Minyaylo, A. V. Zaitsev, V. A. Ol'shevskaya, A. S. Peregudov, A. A. Anisimov, “The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials”, Mendeleev Commun., 33:1 (2023), 47–49  mathnet  crossref
    2. V. A. Vasnev, G. D. Markova, “Recent Advances in the Field of Polycarboranesiloxanes Synthesis”, Polym. Sci. Ser. C, 64:2 (2022), 176  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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