Abstract:
Diene and cyclopentadienyl rhodium halides are very often used as catalysts for various transformations. Herein we analyze the advantages and limitations of classical and more recent synthetic methods for the preparation of these catalysts with a focus on the compounds with chiral ligands.
Citation:
A. V. Kolos, D. S. Perekalin, “Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes”, Mendeleev Commun., 31:1 (2021), 1–7
Linking options:
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This publication is cited in the following 19 articles:
Tatiana N. Petrushina, Yulia V. Nelyubina, Dmitry S. Perekalin, Nikita V. Shvydkiy, “Catalytic activity of cyclobutadiene rhodium complexes in hydrosilylation and other transformations of alkynes”, New J. Chem., 48:9 (2024), 3952
Vladimir B. Kharitonov, Dmitry V. Muratov, Alexey N. Rodionov, Yulia V. Nelyubina, Mher A. Navasardyan, Mikhail S. Nechaev, Dmitry A. Loginov, “Rhodium Catalysts Based on Phenyl Substituted Cp Ligands for Indole Synthesis via Oxidative Coupling of Acetanilides and Alkynes”, Adv Synth Catal, 366:22 (2024), 4729
V. B. Kharitonov, Yu. V. Nelyubina, D. V. Muratov, D. A. Loginov, “Tetrahydrofluorenyl rhodium complexes: positive impact of p-methoxybenzyl substituent on catalytic annulation reactions”, Mendeleev Commun., 34:1 (2024), 57–60
Andrey V. Kolos, Yulia V. Nelyubina, Evgeniya S. Podyacheva, Dmitry S. Perekalin, “Rhodium complexes with planar-chiral cyclopentadienyl ligands: synthesis from tert-butylacetylene and catalytic performance in C–H activation of arylhydroxamates”, Dalton Trans., 52:45 (2023), 17005
Vladimir B. Kharitonov, Dmitry V. Muratov, Yulia V. Nelyubina, Ilya A. Shutkov, Alexey A. Nazarov, Dmitry A. Loginov, “Triphenylcyclopentadienyl Rhodium Complexes in Catalytic C–H Annulations. Application for Synthesis of Natural Isocoumarins”, J. Org. Chem., 88:5 (2023), 2869
Vladimir B. Kharitonov, Evgeniya Podyacheva, Denis Chusov, Yulia V. Nelyubina, Dmitry V. Muratov, Dmitry A. Loginov, “Planar Chiral Rhodium Complex Based on the Tetrahydrofluorenyl Core for Enantioselective Catalysis”, Org. Lett., 25:49 (2023), 8906
T. N. Gribanova, R. M. Minyaev, V. I. Minkin, “Polynuclear sandwich derivatives of [10]annulene: A quantum chemical study”, Mendeleev Commun., 33:3 (2023), 302–305
Andrey V. Kolos, Yulia V. Nelyubina, Dmitry S. Perekalin, “Catalytic and Stoichiometric Reactions of the Parent Olefin Rhodium(I) Complex with Alkynes”, Organometallics, 41:21 (2022), 3038
Roman A. Pototskiy, Mikhail A. Boym, Yulia V. Nelyubina, Dmitry S. Perekalin, “Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor”, Synthesis, 54:21 (2022), 4721
Vladimir B. Kharitonov, Dmitry V. Muratov, Dmitry A. Loginov, “Cyclopentadienyl complexes of group 9 metals in the total synthesis of natural products”, Coordination Chemistry Reviews, 471 (2022), 214744
Nikita V. Shvydkiy, Tatiana N. Petrushina, Dmitry S. Perekalin, “Cyclobutadiene Rhodium Complexes as Catalysts for the Synthesis of Amides from Electron‐rich Arenes, Tosyl Azide and CO”, ChemCatChem, 13:12 (2021), 2873
Nikita M. Ankudinov, Denis A. Chusov, Yulia V. Nelyubina, Dmitry S. Perekalin, “Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E-H Bonds”, Angewandte Chemie, 133:34 (2021), 18860
Nikita M. Ankudinov, Denis A. Chusov, Yulia V. Nelyubina, Dmitry S. Perekalin, “Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E-H Bonds”, Angew Chem Int Ed, 60:34 (2021), 18712
Andrey V. Kolos, Yulia V. Nelyubina, Basker Sundararaju, Dmitry S. Perekalin, “Synthesis of Overloaded Cyclopentadienyl Rhodium(III) Complexes via Cyclotetramerization of tert-Butylacetylene”, Organometallics, 40:22 (2021), 3712
Vladimir B. Kharitonov, Sofiya A. Runikhina, Yulia V. Nelyubina, Dmitry V. Muratov, Denis Chusov, Dmitry A. Loginov, “Easy Access to Versatile Catalytic Systems for C-H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium(III) Complexes”, Chemistry A European J, 27:42 (2021), 10903
Sofya S. Kuvshinova, Yulia V. Nelyubina, Vladimir A. Larionov, Daria V. Vorobyeva, Sergey N. Osipov, Dmitry A. Loginov, “Half-sandwich complexes of group 9 metals with N,Nʹ-ligands for CF3-carbenoid alkylation of N-(pyrimidin-2-yl)indole”, Journal of Organometallic Chemistry, 946-947 (2021), 121899
I. Yu. Titov, V. S. Stroylov, P. V. Rusina, I. Svitanko, “Preliminary modelling as the first stage of targeted organic synthesis”, Russian Chem. Reviews, 90:7 (2021), 831–867
J. Cabanes, M. Odnoroh, C. Duhayon, Ch. Bijani, A. Sournia-Saquet, R. Poli, A. Labande, “Oxidation-promoted synthesis of ferrocenyl planar chiral rhodium(iii) complexes for C–H functionalization catalysis”, Mendeleev Commun., 31:5 (2021), 620–623
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