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Mendeleev Communications, 2022, Volume 32, Issue 6, Pages 798–800
DOI: https://doi.org/10.1016/j.mencom.2022.11.030
(Mi mendc803)
 

This article is cited in 1 scientific paper (total in 1 paper)

Communications

N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure

A. S. Soldatenko, I. V. Sterkhova, N. F. Lazareva

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
Full-text PDF (281 kB) Citations (1)
Abstract: N-(Chlorodimethylsilyl)methyl anilides of formula RC(O)N(C6H4X)CH2SiMe2Cl (R = Me, Ph; X = H, Me, Cl) were obtained by the reaction of N-TMS-containing anilides with ClCH2Si(Hal)Me2 (Hal = F, Cl). The silicon atom in these compounds is pentacoordinate according to the results of NMR and X-ray diffraction analysis.
Keywords: N-(chlorodimethylsilyl)methyl anilides, N-TMS anilides, chloromethyl(dimethyl)halogenosilanes, silicon pentacoordinate, NMR, X-ray diffraction analysis, organosilicon compounds.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.2 Mb)


Citation: A. S. Soldatenko, I. V. Sterkhova, N. F. Lazareva, “N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure”, Mendeleev Commun., 32:6 (2022), 798–800
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  • https://www.mathnet.ru/eng/mendc/v32/i6/p798
  • This publication is cited in the following 1 articles:
    1. Anastasiya S. Soldatenko, Irina V. Sterkhova, Nataliya F. Lazareva, “Synthesis and structure of N-(silylmethyl)benzanilides with SiC3OCl and SiC2OCl2 coordination units”, Journal of Organometallic Chemistry, 987-988 (2023), 122634  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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