Abstract:
N-(Chlorodimethylsilyl)methyl anilides of formula RC(O)N(C6H4X)CH2SiMe2Cl (R = Me, Ph; X = H, Me, Cl) were obtained by the reaction of N-TMS-containing anilides with ClCH2Si(Hal)Me2 (Hal = F, Cl). The silicon atom in these compounds is pentacoordinate according to the results of NMR and X-ray diffraction analysis.
Citation:
A. S. Soldatenko, I. V. Sterkhova, N. F. Lazareva, “N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure”, Mendeleev Commun., 32:6 (2022), 798–800
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https://www.mathnet.ru/eng/mendc803
https://www.mathnet.ru/eng/mendc/v32/i6/p798
This publication is cited in the following 1 articles:
Anastasiya S. Soldatenko, Irina V. Sterkhova, Nataliya F. Lazareva, “Synthesis and structure of N-(silylmethyl)benzanilides with SiC3OCl and SiC2OCl2 coordination units”, Journal of Organometallic Chemistry, 987-988 (2023), 122634