Abstract:
An unusual neutral dinuclear palladium(II) complex with two head-to-head orientated μ-P,S-bridging ligands was obtained by the reaction of Pd(MeCN)2 Cl2 with (1R,5R)-3-(4-phenylthiobutoxy)-2,4-diphenyl-2,4-diaza-3-phospha-bicyclo[3.4.0]nonane. The dimeric structure of the complex in the solid state and in solution was thoroughly confirmed using appropriate analytical techniques: single crystal X-ray diffraction analysis, HRMS, FTIR and NMR spectroscopy.
Citation:
V. S. Zimarev, I. V. Chuchelkin, K. N. Gavrilov, I. A. Zamilatskov, V. A. Tafeenko, B. V. Lokshin, N. S. Goulioukina, “Neutral dinuclear palladium(II) complex containing chiral P,S-bridging diamidophosphite-thioether ligands”, Mendeleev Commun., 34:2 (2024), 195–197
Linking options:
https://www.mathnet.ru/eng/mendc80
https://www.mathnet.ru/eng/mendc/v34/i2/p195
This publication is cited in the following 1 articles:
Narjes Alisufi, Effat Dehghanian, Hassan Mansouri-Torshizi, Fatemeh Mohammadi, Leila Dehghanian, “A novel water-soluble dinuclear Pd(II) complex having 4,4′- bipyridine and diethylenetriamine ligands and its interaction with DNA and BSA”, Journal of Biomolecular Structure and Dynamics, 2025, 1
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