Abstract:
Polyacrylonitrile terpolymers based on acrylonitrile, acrylic acid, and methyl acrylate were synthesized by reversible addition–fragmentation chain-transfer polymerization with varying the monomer addition sequence during the synthesis. The monomer introduction sequence in the synthesis of a ternary copolymer significantly affects both the rheological properties of solutions and the strength of obtained fibers.
Citation:
I. Yu. Skvortsov, L. A. Varfolomeeva, M. S. Kuzin, A. F. Vashchenko, E. V. Chernikova, R. V. Toms, V. G. Kulichikhin, “Effect of the comonomer addition sequence in the synthesis of an acrylonitrile terpolymer on the solution rheology and fiber properties”, Mendeleev Commun., 32:5 (2022), 652–654
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https://www.mathnet.ru/eng/mendc756
https://www.mathnet.ru/eng/mendc/v32/i5/p652
This publication is cited in the following 9 articles:
A. E. Tarasov, A. A. Grishchuk, Yu. V. Podval'naya, E. R. Badamshina, M. V. Mironova, M. S. Kuzin, I. Yu. Skvortsov, V. G. Kulichikhin, “Molecular weight and spinnability of polyacrylonitrile: control with water and 1,8-diazabicyclo[5.4.0]undec-7-ene during anionic polymerization in dimethyl sulfoxide”, Mendeleev Commun., 34:5 (2024), 740–742
Roman V. Toms, Mikhail S. Balashov, Alexander Yu. Gervald, Nikolay I. Prokopov, Anna V. Plutalova, Elena V. Chernikova, “Influence of Monomer Sequence on the Cyclization Behavior of Poly(acrylonitrile-co-acrylamide)”, Applied Sciences, 13:6 (2023), 3734
E. V. Chernikova, M. S. Pavlova, A. V. Plutalova, E. A. Litmanovich, A. L. Maksimov, “Controlled Radical Polymerization of Lauryl Methacrylate in the Synthetic Polyalphaolefin Base Oil”, Dokl Chem, 512:1 (2023), 249
Ivan Yu. Skvortsov, Mikhail S. Kuzin, Andrey F. Vashchenko, Roman V. Toms, Lydia A. Varfolomeeva, Elena V. Chernikova, Gulbarshin K. Shambilova, Valery G. Kulichikhin, “Fiber Spinning of Polyacrylonitrile Terpolymers Containing Acrylic Acid and Alkyl Acrylates”, Fibers, 11:7 (2023), 65
E. V. Chernikova, M. S. Pavlova, A. V. Plutalova, E. A. Litmanovich, A. L. Maksimov, “CONTROLLED RADICAL POLYMERIZATION OF LAURYL METHACRYLATE IN THE BASE SYNTHETIC POLYALPHAOLEFIN OIL”, Doklady Rossijskoj akademii nauk. Himiâ, nauki o materialah., 512:1 (2023), 39
N. I. Osipova, A. V. Plutalova, R. V. Toms, N. I. Prokopov, E. V. Chernikova, “Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole”, Mendeleev Commun., 33:4 (2023), 568–571
R. V. Toms, A. Yu. Gerval'd, M. S. Balashov, N. I. Prokopov, A. V. Plutalova, E.V. Chernikova, “Controlled Copolymerization of Acrylonitrile and Ethyl 2-cyanoacrylate under Reversible Addition-Fragmentation Chain Transfer Conditions and Thermal Behavior of the Obtained Copolymers”, Polym. Sci. Ser. B, 64:6 (2022), 824
N. M. Maksimov, R. V. Toms, M. S. Balashov, A. Yu. Gerval'd, N. I. Prokopov, A. V. Plutalova, M. S. Kuzin, I. Yu. Skvortsov, V. G. Kulichikhin, E. V. Chernikova, “Novel Potential Precursor of Carbon Fiber Based on Copolymers of Acrylonitrile, Acrylamide, and Alkyl Acrylates”, Polym. Sci. Ser. B, 64:5 (2022), 670
Ivan Yu. Skvortsov, Nikita M. Maksimov, Mikhail S. Kuzin, Roman V. Toms, Lydia A. Varfolomeeva, Elena V. Chernikova, Valery G. Kulichikhin, “Influence of Alkyl Acrylate Nature on Rheological Properties of Polyacrylonitrile Terpolymers Solutions, Spinnability and Mechanical Characteristics of Fibers”, Materials, 16:1 (2022), 107
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