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Mendeleev Communications, 2022, Volume 32, Issue 5, Pages 582–584
DOI: https://doi.org/10.1016/j.mencom.2022.09.004 (Mi mendc732) 		 
This article is cited in 5 scientific papers (total in 5 papers)

Communications

Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene

V. A. Dodonov, A. A. Skatova, I. L. Fedushkin

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
Full-text PDF (324 kB) Citations (5)
DOI: https://doi.org/10.1016/j.mencom.2022.09.004
Abstract: Reactivity of ytterbium and magnesium complexes of gallylenes against carbon dioxide and diphenylketene has been assessed. Ytterbium complex of redox-active gallylene [{(dpp-bian)Ga}2Yb(DME)2] (dpp-bian = 1,2-bis[(2,6-diiso-propylphenyl)imino]acenaphthene) on treatment with CO2 gives complex [(dpp-bian)Ga(DME)Me], while the treatment of magnesium-stabilized gallylene[{(dpp-bian)Ga}2Mg(DME)2] with Ph2CCO affords cycloadduct [(dpp-bian)(Ph2CCO)GaMe].
Keywords: gallylenes, carbon dioxide, ketenes, non-innocent α-diimine ligands, cycloaddition, magnesium, ytterbium, X-ray diffraction.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (2.0 Mb)


Citation: V. A. Dodonov, A. A. Skatova, I. L. Fedushkin, “Reactions of ytterbium and magnesium gallylene complexes with carbon dioxide and diphenylketene”, Mendeleev Commun., 32:5 (2022), 582–584
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  • https://www.mathnet.ru/eng/mendc/v32/i5/p582
    • This publication is cited in the following 5 articles:
    1. V. A. Dodonov, A. A. Skatova, I. L. Fedushkin, “Reactivity of the magnesium bisamide complex towards C=C=O-, N=C=O-, and N—N=O-containing substrates”, Russ Chem Bull, 73:3 (2024), 555  crossref
    2. A. N. Lukoyanov, G. V. Markin, G. Yu. Zhigulin, S. Yu. Ketkov, M. A. Lopatin, E. V. Baranov, V. A. Kuropatov, A. A. Belikov, “Synthesis of C1-Symmetric Bulky Redoxi-Active Iminoketones and Diimines of the Pyrene and Aceanthrylene Series”, Russ J Gen Chem, 93:S3 (2023), S649  crossref
    3. V. A. Dodonov, O. A. Kushnerova, E. V. Baranov, I. L. Fedushkin, “Unexpected transformations of an allyl group in a gallium complex with the redox-active dpp-bian ligand”, Russ Chem Bull, 72:11 (2023), 2667  crossref
    4. P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism”, Russ. J. Inorg. Chem., 68:9 (2023), 1228  crossref
    5. P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Raznoligandnyi anionnyi kompleks pivalata kobalta(II) s mostikovym trimetilsiloksoligandom: sintez, stroenie i mekhanizm formirovaniya”, Žurnal neorganičeskoj himii, 68:9 (2023), 1255  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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