Abstract:
We report the radioluminescent properties of the recently discovered hybrid bromocuprate (MeNH3)2CuBr3 in a poly(methyl methacrylate) matrix in the form of solution- produced composite thick films. The obtained films demonstrate bright turquoise photoluminescence in UV light and intense radioluminescence due to CuKα and AgKα radiation at room temperature, exceeding the radioluminescence intensity of Cs4PbBr6@CsPbBr3 films by more than an order of magnitude.
Citation:
S. A. Fateev, D. E. Belikova, D. A. Novichkov, V. G. Petrov, V. V. Utochnikova, E. A. Goodilin, A. B. Tarasov, “Methylammonium bromocuprate (MeNH3)2CuBr3 as a new self-absorption-free solution-processable X-ray scintillator”, Mendeleev Commun., 32:4 (2022), 495–497
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This publication is cited in the following 5 articles:
Sergey A. Fateev, Vladislava Y. Kozhevnikova, Kirill M. Kuznetsov, Daria E. Belikova, Victor N. Khrustalev, Eugene A. Goodilin, Alexey B. Tarasov, “Optical and scintillation properties of hybrid manganese(ii) bromides with formamidinium and acetamidinium cations”, Dalton Trans., 53:6 (2024), 2722
Xinxin Chen, Shujun Zhu, Jiali Han, Tao Zhao, Jianguo Pan, Shangke Pan, “Growth and Optical Properties of Yellow Luminescent [Epy]2[CuBr3] Single Crystals Based on Self Trapping States”, Cryst. Res. Technol., 59:8 (2024)
Daria E. Belikova, Sergey A. Fateev, Victor N. Khrustalev, Vladislava Kozhevnikova, Artem A. Ordinartsev, Alexander V. Dzuban, Eugene A. Goodilin, Alexey B. Tarasov, “Bright luminescence of new low-melting copper(i) chlorides with compact organic cations”, J. Mater. Chem. C, 12:34 (2024), 13537
Peter C. Ford, Advances in Inorganic Chemistry, 83, Photochemistry and Photophysics of Earth-Abundant Transition Metal Complexes, 2024, 269
Daria E. Belikova, Sergey A. Fateev, Victor N. Khrustalev, Ekaterina I. Marchenko, Eugene A. Goodilin, Shenghao Wang, Alexey B. Tarasov, “Exceptional structural diversity of hybrid halocuprates(i) with methylammonium and formamidinium cations”, Dalton Trans., 52:21 (2023), 7152