Abstract:
Novel first-generation dendrimers on the calix[4]resorcinol core with four branches each containing multiple 1,2,3-triazole units have been synthesized in one-step by acid catalyzed condensation of resorcinols with a new aldehyde dendron, namely, 4-{3,5-bis[(1-benzyl-1H-1,2,3-triazol-4-yl)- methoxy]benzyloxy}benzaldehyde (obtained by alkyne–azide cycloaddition). The reaction proceeds stereoselectively to form rccc-diastereoisomers in high yields.
Citation:
I. R. Mironova (Knyazeva), V. V. Syakaev, W. D. Habicher, A. R. Burilov, “Novel first-generation dendrimers on calix[4]resorcinol core equipped with multiple triazole units”, Mendeleev Commun., 32:1 (2022), 103–104
Linking options:
https://www.mathnet.ru/eng/mendc585
https://www.mathnet.ru/eng/mendc/v32/i1/p103
This publication is cited in the following 2 articles:
I. R. Mironova (Knyazeva), V. V. Syakaev, W. D. Habicher, A. R. Burilov, “New calix[4]resorcinol rccc diastereoisomer with terminal triple bonds: Synthesis, structural features and reactions”, Mendeleev Commun., 33:3 (2023), 397–400
I. R. Mironova (Knyazeva), N. P. Romashov, V. V. Syakaev, D. P. Gerasimova, O. A. Lodochnikova, A. R. Burilov, “Efficient synthesis of calix[4]resorcinol rccc diastereoisomers using high amount of trifluoroacetic acid in the chloroform medium”, Mendeleev Commun., 33:6 (2023), 844–846
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