Abstract:
Reaction of 2,3,4,6-tetra-O-acetyl-D-glucal with allyltrimethylsilane, methyl 3-mercaptopropionate, methyl (6R)-6-benzoyloxy-7-oxyheptanoate or glycolic acid methyl ester, catalysed by boron trifluride etherate, leads preferentially to the a-anomers of unsaturated 2’-oxo-C-, S- or O-glycosides.
Document Type:
Article
Language: English
Citation:
A. G. Tolstikov, E. E. Savateeva, L. V. Spirikhin, G. A. Tolstikov, “New Chirones Prepared from 2-Acetoxyglucal”, Mendeleev Commun., 1:4 (1991), 133–134
Linking options:
https://www.mathnet.ru/eng/mendc5543
https://www.mathnet.ru/eng/mendc/v1/i4/p133
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