Abstract:
Thermolysis of (OC)5ReC≡CPh in refluxing toluene yields the binuclear complex Re2(CO)7(C2Ph)4 2, characterized by an X-ray diffraction study; 2 contains a rheniacyclopentadiene moiety, formed by coupling of four PhC≡C groups, two of which undergo additional annelation producing the 1-phenylnaphthalene system.
Document Type:
Article
Language: English
Citation:
A. A. Koridze, V. I. Zdanovich, A. S. Batsanov, Yu. T. Struchkov, “Annelation of Phenylacetylide Groups by Thermolysis of (OC)5ReC≡CPh. X-Ray Crystal Structure of Re2(CO)7(C2Ph)4”, Mendeleev Commun., 1:4 (1991), 126–127
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https://www.mathnet.ru/eng/mendc5538
https://www.mathnet.ru/eng/mendc/v1/i4/p126
This publication is cited in the following 5 articles:
Claudia Cardozo, Axel Mendoza, Gabriela Farías, André Luiz Barboza Formiga, Deisy Peña, Franmerly Fuentes, Alejandro Arce, Yomaira Otero, “Synthesis of rhenacyclopentadienes and η2:η2-diyne complexes from a labile dirhenium carbonyl and π-conjugated 1,7-octadiynes: Structural and photophysical characterization”, Journal of Organometallic Chemistry, 881 (2019), 34
Shinsaku Yamazaki, “Rearrangements of alkyne and 1,3-diyne in transition metal center forming small ring complexes”, Inorganica Chimica Acta, 366:1 (2011), 1
A.P. Sadimenko, Comprehensive Heterocyclic Chemistry III, 2008, 1243
Shahram Mihan, Torsten Weidmann, Volker Weinrich, Dieter Fenske, Wolfgang Beck, “Kohlenwasserstoffverbrückte Metallkomplexe, XXXIX Zur Chemie von Pentacarbonylrheniumacetyliden”, Journal of Organometallic Chemistry, 541:1-2 (1997), 423
A.A. Koridze, V.I. Zdanovich, O.A. Kizas, A.I. Yanovsky, Yu.T. Struchkov, “Coupling and annelation of two acetylide groups and alkyne molecules in the reaction of (OC)5ReCCPh with ferrocenylacetylene. Crystal and molecular structure of Re2(CO)7{C8H2Ph2(C5H4FeC5H5)2} · acetone”, Journal of Organometallic Chemistry, 464:2 (1994), 197
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