Abstract:
The reaction of [Pd(OAc)2(PPh3)]2 with HCO2H includes the transfer of an O atom from the carboxylic ligand to the P atom and cleavage of the P—Ph bond accompanied by transfer of the Ph group from PPh3 ligand to the palladium atom; the structure of the complex formed, [Pd(μ-O2PPh2)(C6H5)(PPh3)]2, has been resolved by X-ray analysis.
Document Type:
Article
Language: English
Citation:
N. Yu. Kozitsyna, A. M. Ellern, M. Yu. Antipin, Yu. T. Struchkov, I. I. Moiseev, “Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd( μ-O2PPh2)(C6H5)(PPh3)]2”, Mendeleev Commun., 1:3 (1991), 92–94
Linking options:
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Homogeneous Catalysis with Metal Complexes, 2012, 453
Vimal K. Jain, Leela Jain, “The chemistry of binuclear palladium(II) and platinum(II) complexes”, Coordination Chemistry Reviews, 249:24 (2005), 3075
Vladimir V. Grushin, “Mixed Phosphine-Phosphine Oxide Ligands”, Chem. Rev., 104:3 (2004), 1629
Vladimir V. Grushin, “Synthesis of Hemilabile Phosphine-Phosphine Oxide Ligands via the Highly Selective Pd-Catalyzed Mono-oxidation of Bidentate Phosphines: Scope, Limitations, and Mechanism”, Organometallics, 20:18 (2001), 3950
Vladimir V. Grushin, “Catalysis for Catalysis: Synthesis of Mixed Phosphine-Phosphine Oxide Ligands via Highly Selective, Pd-Catalyzed Monooxidation of Bidentate Phosphines”, J. Am. Chem. Soc., 121:24 (1999), 5831
Vimal K Jain, Ray J Butcher, “Synthesis and structure of binuclear complexes of palladium and platinum containing bridging diphenylphosphinate ligand”, Polyhedron, 17:8 (1998), 1317
Allan J. Canty, Comprehensive Organometallic Chemistry II, 1995, 225
N. Yu. Kozitsyna, I. I. Moiseev, “Reduction methods in the synthesis of low-valence platinum and palladium complexes”, Russian Chem. Reviews, 64:1 (1995), 47–60
Ilya I. Moiseev, Tatiana A. Stromnova, Michael N. Vargaftik, “Palladium clusters: Stoichiometric and catalytic reactions”, Journal of Molecular Catalysis, 86:1-3 (1994), 71
Ann K. Keep, “Palladium”, Coordination Chemistry Reviews, 127:1-2 (1993), 99
Ilya I. Moiseev, Natalya Yu. Kozitsyna, Dmitry I. Kochubey, Vsevolod N. Kolomijchuk, Kirill I. Zamaraev, “Synthesis and characterization of platinum and palladium clusters with phosphide ligands”, Journal of Organometallic Chemistry, 451:1-2 (1993), 231
Ilya I. Moiseev, Tatiana A. Stromnova, Irina N. Busygina, Natalya Yu. Tihonova, Natalya Yu. Kozitsyna, Arkady M. Ellern, Mikhail Yu. Antipin, Yury T. Struchkov, “Oxidation of bridging groups by carboxylate coordinated ligands in palladium clusters”, J Clust Sci, 3:4 (1992), 411
Ilya I. Moiseev, N. Yu. Kozitsyna, D. I. Kochubey, K. I. Zamaraev, “Platinum Clusters with Phosphide Ligands: Synthesis and Characterization”, MRS Proc., 272 (1992)
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