Abstract:1H NMR spectral data and an X-ray structural analysis of 5-acyloxy-5-benzyl-1,2,3,4-tetraphenylcyclopenta-1,3-diene have elucidated the 3,3-sigmatropic shift pathway of circumambulation of the acyloxy group around the cyclopentadiene ring.
Document Type:
Article
Language: English
Citation:
I. E. Mikhailov, G. A. Dushenko, I. A. Kamenetskaya, O. E. Kompan, Yu. T. Struchkov, V. I. Minkin, “3,3-Sigmatropic Shift Mechanism for Circumambulation of Acyloxy Groups around the Cyclopentadiene Ring”, Mendeleev Commun., 1:3 (1991), 83–84
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This publication is cited in the following 5 articles:
Sergei M. Lukyanov, Alla V. Koblik, Patai's Chemistry of Functional Groups, 2009
V. I. Minkin, I. E. Mikhailov, G. A. Dushenko, O. E. Kompan, A. Zschunke, “Fast and reversible migrations of N,S-centered groups around the perimeter of cyclopropene and cycloheptatriene rings”, Russ Chem Bull, 47:5 (1998), 884
Igor E. Mikhailov, Galina A. Dushenko, Igor D. Sadekov, Adolf Zschunke, Vladimir I. Minkin, “Circumambulatory Rearrangements of O-, S-, Se-, and Te- Centred Groups Around the Cyclopentadiene Ring”, Phosphorus, Sulfur, and Silicon and the Related Elements, 136:1 (1998), 541
I. E. Mikhailov, G. A. Dushenko, O. E. Kompan, Yu. T. Struchkov, A. Zschunke, C. Muegge, V. N. Drozd, V. I. Minkin, “Circumambulatory Rearrangements of Dithioacyloxy Groups around the Cyclopentadiene Ring”, Mendeleev Commun., 4:4 (1994), 120–122
I. E. Mikhailov, G. A. Dushenko, A. V. Kisin, C. Muegge, A. Zschunke, V. I. Minkin, “1,5-Sigmatropic Shifts of Chlorine in the Cyclopentadiene Ring”, Mendeleev Commun., 4:3 (1994), 85–88
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