Abstract:
Complete and partial O-functionalization of the octahydroxytetramethyl[14]metacyclophane with phosphoryl groups has been carried out, arid reversible intramolecular addition of hydroxy or trimethylsilyloxy groups to the neighbouring P=O bonds with the formation of spirophosphorane fragments has been shown to be typical of the 3,10,17,24-tetrahydroxy(tetrakistrimethylsilbxy)-5,12,19,26-tetrakis-o-phenylenephosphoryloxy-1,8,15,22-tetramethyl [14]metacyclophane.
Document Type:
Article
Language: English
Citation:
L. N. Markovsky, V. I. Kalchenko, D. M. Rudkevich, A. N. Shivanyuk, “Phosphorylated Resorcinol-based Cyclophanes”, Mendeleev Commun., 2:3 (1992), 106–108
Linking options:
https://www.mathnet.ru/eng/mendc5428
https://www.mathnet.ru/eng/mendc/v2/i3/p106
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