Abstract:
The reaction of trans-[(PPh3)PtCI2]2 with AgOAc in HOAc gives the new tetranuciear complex [(PPh3)Pt(μ2-OAc)2(μ3-OAc)Ag]2, In which the Ag and Pt atoms are bonded by bridging bi- and tri-coordinated acetate ligands, according to single crystal X-ray data.
Document Type:
Article
Language: English
Citation:
N. Yu. Kozitsyna, A. M. Ellern, Yu. T. Struchkov, I. Yu. Moiseev, “Synthesis and Molecular Structure of the Tetranuclear Complex [(PPh3)Pt(μ2-OAc)2(μ3-OAc)Ag]2”, Mendeleev Commun., 2:3 (1992), 100–102
Linking options:
https://www.mathnet.ru/eng/mendc5424
https://www.mathnet.ru/eng/mendc/v2/i3/p100
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Nicola Oberbeckmann-Winter, Xavier Morise, Pierre Braunstein, Richard Welter, “Synthesis and Structure of Pt(II) Phosphonato-Phosphine Complexes and of a P,O-Stabilized Metal-Metal-Bonded Pt2Ag2Complex”, Inorg. Chem., 44:5 (2005), 1391
M.C. Gimeno, A. Laguna, Comprehensive Coordination Chemistry II, 2003, 911
David R. Whitcomb, Robin D. Rogers, “The molecular structure of catena-[(μ-phthalato)-di-(μ-phthalazine(-di-silver(I)hydrate] ([Ag2(μ-(O2C)2C6H4)(μ-PHZ)2(H2O)]n): carboxylate control of side-on versus stacked coordination polymerization”, Inorganica Chimica Acta, 256:2 (1997), 263
Rafael Usón, Juan Forniés, Milagros Tomás, Raquel Garde, Rosa I. Merino, “Synthesis of Heteronuclear Pt-Tl Complexes with Donor-Acceptor Bonds. X-ray Structures of cis-[Tl(μ2-OOCCH3)Pt(PPh3)(C6F5)2] and (NBu4)2[{Pt(C6F5)3}2{(μ2-O,μ3-O'CCH3)Tl}2]”, Inorg. Chem., 36:7 (1997), 1383
N. Kositzyna, M. Antipin, K. Lyssenko, P.S. Pregosin, G. Trabesinger, “Synthesis and characterisation of Pd(II) allyl complexes derived from the diterpene carvone”, Inorganica Chimica Acta, 250:1-2 (1996), 365
Ilya I. Moiseev, Natalya Yu. Kozitsyna, Dmitry I. Kochubey, Vsevolod N. Kolomijchuk, Kirill I. Zamaraev, “Synthesis and characterization of platinum and palladium clusters with phosphide ligands”, Journal of Organometallic Chemistry, 451:1-2 (1993), 231
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