Abstract:
Norbornadiene tetramers exo-trans-exo-trans-exo-endo-dodecacyclo[14.9.1.14,13.17,10.02,15.03,14.05,12.06,11.017,25.018,23.019,21.020,24]octacos-8-ene 2 and exo-trans-exo-trans-exo-exo-dodecacyclo[14.9.1.14,13.17,10.02,15.03,14.05,12.06,11.017,25.018,23.019,21.020.24]octanos-8-ene 3 have been synthesized in 32% total yield, via Pd complex catalysed cyclodimerization of a known norbornadiene trimer exo-trans-exo-trans-exo-octacyclo[8.8.1.14,7.113,16.02,9.03,8.011,18.012,17]henicosa-5,14-diene 1 with quadricyclane.
Document Type:
Article
Language: English
Citation:
U. M. Dzhemilev, R. I. Khusnutdinov, D. Kh. Galeev, A. I. Malikov, O. M. Nefedov, Yu. V. Tomilov, “The First Synthesis of Norbornadiene Tetramers”, Mendeleev Commun., 2:2 (1992), 56–57
Linking options:
https://www.mathnet.ru/eng/mendc5401
https://www.mathnet.ru/eng/mendc/v2/i2/p56
This publication is cited in the following 3 articles:
L. M. Khalilov, O. V. Shitikova, R. I. Khusnutdinov, U. M. Dzhemilev, “13C NMR spectra of polycyclic compounds. Bicyclo[2.2.1]heptadiene tetramers”, Russ Chem Bull, 47:12 (1998), 2463
R. I. Khusnutdinov, D. K. Galeev, A. I. Malikov, U. M. Dzhemilev, O. M. Nefedov, “Codimerization of quadricyclane withendo,exo-hexacyclo[9.2.1.02,10.03,8.04,6.05,9]tetradec-12-ene catalyzed by the Pd(PPh3)4 complex”, Russ Chem Bull, 43:11 (1994), 1871
U. M. DZHEMILEV, R. I. KHUSNUTDINOV, D. KH. GALEEV, A. I. MALIKOV, O. M. NEFEDOV, YU. V. TOMILOV, “ChemInform Abstract: The First Synthesis of Norbornadiene Tetramers.”, ChemInform, 23:39 (1992)