R. R. Rakhimov, A. I. Semikopny, Ya. S. Lebedev, “Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals”, Mendeleev Commun., 2:1 (1992), 2

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Mendeleev Communications, 1992, Volume 2, Issue 1, Pages 2–4
DOI: https://doi.org/10.1070/MC1992v002n01ABEH000093 (Mi mendc5364)

This article is cited in 1 scientific paper (total in 1 paper)

Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals

R. R. Rakhimov^a, A. I. Semikopny^b, Ya. S. Lebedev^c

^a V.I. Nikitin Institute of Chemistry, Academy of Sciences of the Tajikistan, Dushanbe, Tajikistan
^b Institute of Chemistry, Tadzhik Academy of Sciences
^c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (679 kB) Citations (1)

DOI: https://doi.org/10.1070/MC1992v002n01ABEH000093

Abstract: The spin exchange dynamics and the rotational mobility of rigid-frame nitroxide biradicals have been studied by EPR; despite the intramolecular character of the exchange, its rate correlates with molecular mobility, being damped in viscous media, thus proving that even the simplest intramolecular reactions are controlled by molecular dynamics.

Document Type: Article

Language: English

Citation: R. R. Rakhimov, A. I. Semikopny, Ya. S. Lebedev, “Unexpected Influence of Viscosity on Intramolecular Spin Exchange in Nitroxide Biradicals”, Mendeleev Commun., 2:1 (1992), 2–4

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This publication is cited in the following 1 articles:

R. R. Rakhimov, A. I. Prokof'ev, Ya. S. Lebedev, “Relation between molecular and chemical dynamics for elementary radical reactions in viscous media”, Russian Chem. Reviews, 62:6 (1993), 509–526

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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