Abstract:
Reaction of [Cp*lr(CO)2] (Cp*=η5-C5Me5) with gaseous HCl leads to formation of the protonated ion, [Cp*lr(CO)2H]+, both in supercritical xenon solution and in a low density polyethylene film.
Document Type:
Article
Language: English
Citation:
S. G. Kazarian, M. Jobling, M. Poliakoff, “IR Spectroscopy of Charged Species in Supercritical Fluid Solution and in Polymer Films; the Protonation of [(η5-C5Me5)lr(CO)2] by HCI”, Mendeleev Commun., 3:4 (1993), 148–149
Linking options:
https://www.mathnet.ru/eng/mendc5304
https://www.mathnet.ru/eng/mendc/v3/i4/p148
This publication is cited in the following 9 articles:
O.A. Kizas, S.K. Moiseev, I.S. Chaschin, I.A. Godovikov, F.M. Dolgushin, A.R. Khokhlov, “New unsaturated sulfur-containing heterocycles derived from 1,3-dithiane or 1,3,5-trithiane and α -ferrocenylvinyl cation generated from ethynylferrocene”, Journal of Organometallic Chemistry, 968-969 (2022), 122358
O.A. Kizas, S.K. Moiseev, I.S. Chaschin, M.I. Godovikova, F.M. Dolgushin, A.R. Khokhlov, “Sulfonium salts derived from α-ferrocenylvinyl cation in situ generated in sc-CO2 from ethynylferrocene by nafion film”, The Journal of Supercritical Fluids, 152 (2019), 104544
Lina M. Epstein, Natalia V. Belkova, Elena S. Shubina, Recent Advances in Hydride Chemistry, 2001, 391
Jawwad A. Darr, Martyn Poliakoff, “New Directions in Inorganic and Metal-Organic Coordination Chemistry in Supercritical Fluids”, Chem. Rev., 99:2 (1999), 495
L. M. Epstein, E. S. Shubina, “Proton transfer and hydrogen bonding with transition metal atoms and hydride hydrogen by IR and NMR studies”, Ber Bunsenges Phys Chem, 102:3 (1998), 359
Sergei G. Kazarian, “Applications of FTIR Spectroscopy to Supercritical Fluid Drying, Extraction and Impregnation”, Applied Spectroscopy Reviews, 32:4 (1997), 301
Martyn Poliakoff, Steven M. Howdle, Sergei G. Kazarian, “Vibrational Spectroscopy in Supercritical Fluids: From Analysis and Hydrogen Bonding to Polymers and Synthesis”, Angew. Chem. Int. Ed. Engl., 34:12 (1995), 1275
Martyn Poliakoff, Steven M. Howdle, Sergei G. Kazarian, “Schwingungsspektroskopie in überkritischen fluiden Phasen: von der Analytik bis zur Synthesechemie”, Angewandte Chemie, 107:12 (1995), 1409
Steven M. Howdle, Martyn Poliakoff, Supercritical Fluids, 1994, 527