This article is cited in 41 scientific papers (total in 41 papers)
Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes
Abstract:
The d-election transition metal-substituted heteropolytungstate sandwich complex [(FeII)4(B–PW9O34)2]10−, unlike PW12O403− and most polytungstophosphates, is quite stable with respect to solvolysis by H2O2 and catalyses the selective homogeneous epoxidation of alkenes in aqueous acetonitrile at 20°C by this oxidant.
Document Type:
Article
Language: English
Citation:
A. M. Khenkin, C. L. Hill, “Selective Homogeneous Catalytic Epoxidation of Alkenes by Hydrogen Peroxide Catalysed by Oxidatively- and Solvolytically-resistant Polyoxometalate Complexes”, Mendeleev Commun., 3:4 (1993), 140–141
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This publication is cited in the following 41 articles:
Paulus Hengky Abram, Robert C. Burns, Lichun Li, “Three- and two-site heteropolyoxotungstate anions as catalysts for the epoxidation of allylic alcohols by H2O2 under biphasic conditions: Reactivity and kinetic studies of the [Ni3(OH2)3(B-PW9O34){WO5(H2O)}]7-, [Co3(OH2)6(A-PW9O34)2]12-, and [M4(OH2)2(B-PW9O34)2]10- anions, where M = Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)”, Inorganica Chimica Acta, 499 (2020), 119178
Isabel C.M.S. Santos, José A.F. Gamelas, Tiago A.G. Duarte, Mário M.Q. Simões, M. Graça P.M.S. Neves, José A.S. Cavaleiro, Ana M.V. Cavaleiro, “Catalytic homogeneous oxidation of monoterpenes and cyclooctene with hydrogen peroxide in the presence of sandwich-type tungstophosphates [M4(H2O)2(PW9O34)2]n-, M = CoII, MnII and FeIII”, Journal of Molecular Catalysis A: Chemical, 426 (2017), 593
Farrokhzad Mohammadi Zonoz, Fatemeh Aliabadi, “A new sandwich-type polyoxometalates containing mixed transition metals, [Cd 2 Zn 2 (H 2 O) 2 (P 2 W 15 O 56 ) 2 ] 16- : Syntheses, spectrochemical characterization and its electrocatalytical activity comparison with [M 4 (H 2 O) 2 (P 2 W 15 O 56 ) 2 ] 16- (M = Cd 2+ and Zn 2+ ) and [P 2 W 15 O 56 ] 12-”, Inorganica Chimica Acta, 444 (2016), 87
Mostafa Riahi Farsani, Fariba Jalilian, Bahram Yadollahi, Hadi Amiri Rudbari, “Comparison between various Keggin and Wells–Dawson sandwich‐type polyoxometalates in catalytic oxidation of cyclooctene and cyclohexene with hydrogen peroxide”, Applied Organom Chemis, 29:1 (2015), 7
Mostafa Riahi Farsani, Elham Assady, Fariba Jalilian, Bahram Yadollahi, Hadi Amiri Rudbari, “Green oxidation of alcohols with hydrogen peroxide catalyzed by a tetra-cobalt polyoxometalate in water”, J IRAN CHEM SOC, 12:7 (2015), 1207
Floriant Doungmene, Pablo A. Aparicio, Joseline Ntienoue, Charyle S. Ayingone Mezui, Pedro de Oliveira, Xavier López, Israël M. Mbomekallé, “Electrochemical behaviour of mixed d metal-iron containing Wells-Dawson sandwich-type complexes: [(FeOH2)2M2(X2W15O56)2]- and [(MOH2)2Fe2(X2W15O56)2]- (M = CrIII, MnIII, MnII, CoII, NiII, CuII, ZnII, X = AsV or PV and n = 12 or 14)”, Electrochimica Acta, 125 (2014), 674
Salete S. Balula, Carlos M. Granadeiro, André D.S. Barbosa, Isabel C.M.S. Santos, Luís Cunha-Silva, “Multifunctional catalyst based on sandwich-type polyoxotungstate and MIL-101 for liquid phase oxidations”, Catalysis Today, 210 (2013), 142
Pragati A Shringarpure, Anjali Patel, “Supported Undecaphosphotungstate: An Ecofriendly and Efficient Solid Catalyst for Nonsolvent Liquid-Phase Aerobic Epoxidation of Alkenes”, Ind. Eng. Chem. Res., 50:15 (2011), 9069
Serena Berardi, Mauro Carraro, Andrea Sartorel, Gloria Modugno, Marcella Bonchio, “Hybrid Polyoxometalates: Merging Organic and Inorganic Domains for Enhanced Catalysis and Energy Applications”, Israel Journal of Chemistry, 51:2 (2011), 259
Ronny Neumann, Modern Oxidation Methods, 2010, 315
Israel M. Mbomekalle, Pierre Mialane, Anne Dolbecq, Jérôme Marrot, Francis Sécheresse, Patrick Berthet, Bineta Keita, Louis Nadjo, “Rational Synthesis, Structure, Magnetism and Electrochemistry of Mixed Iron–Nickel‐Containing Wells–Dawson‐Fragment‐Based Sandwich‐Type Polyoxometalates”, Eur J Inorg Chem, 2009:34 (2009), 5194
Valeria Conte, Olga Bortolini, Patai's Chemistry of Functional Groups, 2009
Jianmin Wang, Liang Yan, Guang Qian, Shunqing Li, Keli Yang, Haitao Liu, Xiaolai Wang, “Na4H3[SiW9Al3(H2O)3O37]·12H2O/H2O: a new system for selective oxidation of alcohols with H2O2 as oxidant”, Tetrahedron, 63:8 (2007), 1826
Ronny Neumann, Transition Metals for Organic Synthesis, 2004, 415
Dorit Sloboda‐Rozner, Peter Witte, Paul L. Alsters, Ronny Neumann, “Aqueous Biphasic Oxidation: A Water‐Soluble Polyoxometalate Catalyst for Selective Oxidation of Various Functional Groups with Hydrogen Peroxide”, Adv Synth Catal, 346:2-3 (2004), 339
Laurent Ruhlmann, Guillaume Genet, “Wells–Dawson-derived tetrameric complexes {K28H8[P2W15Ti3O60.5]4} electrochemical behaviour and electrocatalytic reduction of nitrite and of nitric oxide”, Journal of Electroanalytical Chemistry, 568 (2004), 315
E.M. Limanski, D. Drewes, E. Droste, R. Böhner, B. Krebs, “Syntheses and X-ray characterisation of novel tellurium-substituted lacunary polyoxotungstates containing VIV, CoII, NiII and ZnII as heteroatoms”, Journal of Molecular Structure, 656:1-3 (2003), 17
C.L. Hill, Comprehensive Coordination Chemistry II, 2003, 679
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