Abstract:
The decay rates (Kc = 3×103−109 s−1) of radical anions of polyfluorobenzoates and the redox potentials of radical anion decay products have been determined by photoelectron injection from mercury into aqueous electrolyte solutions (PIMES).
Document Type:
Article
Language: English
Citation:
V. V. Konovalov, Yu. D. Tsvetkov, I. I. Bilkis, S. S. Laev, V. D. Shteingarts, “The Decay Rates of Radical Anions of Polyfluorobenzoic Acids in Water”, Mendeleev Commun., 3:2 (1993), 51–53
Linking options:
https://www.mathnet.ru/eng/mendc5261
https://www.mathnet.ru/eng/mendc/v3/i2/p51
This publication is cited in the following 10 articles:
Vitalij D. Shteingarts, “Recent advances in practice and theory of polyfluoroarene hydrodehalogenation”, Journal of Fluorine Chemistry, 128:7 (2007), 797
M. M. Vyushkova, V. P. Vysotsky, I. V. Beregovaya, L. N. Shchegoleva, V. A. Bagryansky, Yu. N. Molin, “Optically detected ESR spectrum of decafluorobiphenyl radical anions”, Mendeleev Commun., 16:3 (2006), 151–152
A. G. Krivenko, A. S. Kotkin, V. A. Kurmaz, “Thermodynamic and kinetic characteristics of intermediates of electrode reactions: A comparative investigation of a number of alkylaryl and alkyl halide radicals by the laser photoemission methods”, Russ J Electrochem, 41:2 (2005), 137
Valery V. Konovalov, Sergey S. Laev, Irina V. Beregovaya, Lyudmila N. Shchegoleva, Vitalij D. Shteingarts, Yuri D. Tsvetkov, Itzhak Bilkis, “Fragmentation of Radical Anions of Polyfluorinated Benzoates”, J. Phys. Chem. A, 104:2 (2000), 352
Sergey S Laev, Vitalii D Shteingarts, “Reductive dehalogenation of polyfluoroarenes by zinc in aqueous ammonia”, Journal of Fluorine Chemistry, 96:2 (1999), 175
Vyacheslav I. Krasnov, Vyacheslv E. Platonov, Irina V. Beregovaya, Lyudmila N. Shohegoleva, “Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-D-DMF-H2O.”, Tetrahedron, 53:5 (1997), 1797
Lian C. T. Shoute, Jai P. Mittal, “Formation of Radical Anions on the Reduction of Carbonyl-Containing Perfluoroaromatic Compounds in Aqueous Solution: A Pulse Radiolysis Study”, J. Phys. Chem., 100:33 (1996), 14022
Lian C. T. Shoute, Jai P. Mittal, P. Neta, “Reduction and Defluorination of Pentafluorophenol in Aqueous Solutions”, J. Phys. Chem., 100:8 (1996), 3016
Lian C. T. Shoute, Jai P. Mittal, P. Neta, “Fluoride Elimination upon Reaction of Pentafluoroaniline with H, and OH Radicals in Aqueous Solution”, J. Phys. Chem., 100:27 (1996), 11355
Sergey S Laev, Vitalij D Shteingarts, Isaak I Bilkis, “On the difference in the results of reductive defluorination of pentafluorobenzoic acid by sodium and zinc in liquid ammonia medium”, Tetrahedron Letters, 36:26 (1995), 4655
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