Abstract:
A [η6-benzylcopper(I)]tricarbonylchromium complex has been obtained and its 1,4-addition reaction with methyl vinyl ketone carried out, while a convenient method for the 1,2-addition of benzyllithium derivatives of (η6-alkylarene)tricarbonylchromium complexes to carbonyl compounds has been elaborated.
Document Type:
Article
Language: English
Citation:
V. N. Kalinin, I. A. Cherepanov, S. K. Moiseev, “1,2- and 1,4-Addition Reactions of α-Metallated η6-Alkylarene)tricarbonylchromium Complexes to Carbonyl Compounds”, Mendeleev Commun., 3:2 (1993), 43–45
Linking options:
https://www.mathnet.ru/eng/mendc5256
https://www.mathnet.ru/eng/mendc/v3/i2/p43
This publication is cited in the following 5 articles:
Hui Zhu(s), Yu Wu, Jianyou Mao, Jingkai Xu, Patrick J. Walsh, Hang Shi, “C–H functionalization through benzylic deprotonation with π-coordination or cation–π-interactions”, Chem. Soc. Rev., 2025
Motokazu Uemura, Organic Reactions, 2006, 217
Valery N. Kalinin, Il'ya A. Cherepanov, Sergey K. Moiseev, “Benzylic functionalization of (η6-alkylarene)chromium tricarbonyl complexes”, Journal of Organometallic Chemistry, 536-537 (1997), 437
Louis S. Hegedus, “Transition metals in organic synthesis. Annual survey covering the year 1993”, Coordination Chemistry Reviews, 141 (1995), 153
V. N. KALININ, I. A. CHEREPANOV, S. K. MOISEEV, “ChemInform Abstract: 1,2‐ and 1,4‐Addition Reactions of α‐Metallated (η6‐ Alkylarene)tricarbonylchromium Complexes to Carbonyl Compounds.”, ChemInform, 25:33 (1994)
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