Abstract:
Reactions of organomanganese derivatives of 3-sulfolene and 2-methyl-3-sulfolene with allyl- and propargyl bromides result in high yields of related 2-substituted or 2,5-disubstituted 3-sulfolenes; thermolysis of the cross-coupled products gives 1,3,6-trienes or 1,3-dien-6-ynes.
Document Type:
Article
Language: English
Citation:
A. N. Kasatkin, Yu. A. Prokopenko, A. M. Khabibov, G. A. Tolstikov, “Cross-coupling of Organomanganese Derivatives of 3-Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalised Dienes”, Mendeleev Commun., 3:1 (1993), 17–18
Linking options:
https://www.mathnet.ru/eng/mendc5244
https://www.mathnet.ru/eng/mendc/v3/i1/p17
This publication is cited in the following 6 articles:
Goverdhan Mehta, H. Surya Prakash Rao, Patai's Chemistry of Functional Groups, 2009
Lilian A. Radesca, Encyclopedia of Reagents for Organic Synthesis, 2001
Ta‐Shue Chou, Chin‐Jyh Chang, “The Effect of Lithium Ion on the Regioselectivity of Substitution Reactions of Zinc Sulfolenylate”, J Chinese Chemical Soc, 45:4 (1998), 529
Louis S. Hegedus, “Transition metals in organic synthesis. Annual survey covering the year 1993”, Coordination Chemistry Reviews, 141 (1995), 153
A. N. KASATKIN, YU. A. PROKOPENKO, A. M. KHABIBOV, G. A. TOLSTIKOV, “ChemInform Abstract: Cross‐Coupling of Organomanganese Derivatives of 3‐Sulfolenes with Allyl and Propargyl Bromides. A Simple Synthesis of Functionalized Dienes.”, ChemInform, 25:32 (1994)
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