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Mendeleev Communications, 1993, Volume 3, Issue 1, Pages 10–11
DOI: https://doi.org/10.1070/MC1993v003n01ABEH000196
(Mi mendc5239)
 

This article is cited in 11 scientific papers (total in 11 papers)

Selectivity Control by Oxygen Pressure in Methane Oxidation over Phosphate Catalysts

M. Yu. Sineva, S. Setiadib, K. Otsukab

a N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
b Tokyo Institute of Technology
Abstract: Selectivity shifts from formaldehyde to ethane with oxygen pressure and temperature variation in methane oxidation over phosphate catalysts are evidence for the existence of mutual intermediate and different product selectivities over different catalysts under the same reaction conditions, indicating the participation of the surface in formaldehyde formation.1Fax: +7 095 938 2156.2Fax: +81 3 3729 0542.
Document Type: Article
Language: English


Citation: M. Yu. Sinev, S. Setiadi, K. Otsuka, “Selectivity Control by Oxygen Pressure in Methane Oxidation over Phosphate Catalysts”, Mendeleev Commun., 3:1 (1993), 10–11
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  • https://www.mathnet.ru/eng/mendc5239
  • https://www.mathnet.ru/eng/mendc/v3/i1/p10
  • This publication is cited in the following 11 articles:
    1. Nicholas F. Dummer, David J. Willock, Qian He, Mark J. Howard, Richard J. Lewis, Guodong Qi, Stuart H. Taylor, Jun Xu, Don Bethell, Christopher J. Kiely, Graham J. Hutchings, “Methane Oxidation to Methanol”, Chem. Rev., 123:9 (2023), 6359  crossref
    2. V. I. Lomonosov, M. Yu. Sinev, “Oxidative coupling of methane: Mechanism and kinetics”, Kinet Catal, 57:5 (2016), 647  crossref
    3. S. Arndt, R. Schomäcker, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2014  crossref
    4. M. Yu. Sinev, Z.T. Fattakhova, V.I. Lomonosov, Yu. A. Gordienko, “Kinetics of oxidative coupling of methane: Bridging the gap between comprehension and description”, Journal of Natural Gas Chemistry, 18:3 (2009), 273  crossref
    5. Beata Michalkiewicz, Joanna Sreńscek-Nazzal, Piotr Tabero, Barbara Grzmil, Urszula Narkiewicz, “Selective methane oxidation to formaldehyde using polymorphic T-, M-, and H-forms of niobium(V) oxide as catalysts”, Chemical Papers, 62:1 (2008)  crossref
    6. Mikhail Sinev, Vladimir Arutyunov, Andrey Romanets, Advances in Chemical Engineering, 32, Chemical Engineering Kinetics, 2007, 167  crossref
    7. M. Yu. Sinev, “Free radicals as intermediates in catalytic oxidation of light alkanes: new opportunities”, Res. Chem. Intermed., 32:3-4 (2006), 205  crossref
    8. Kiyoshi Otsuka, Ye Wang, “Direct conversion of methane into oxygenates”, Applied Catalysis A: General, 222:1-2 (2001), 145  crossref
    9. L Alemany, “Catalytic activity in partial oxidation of methane and physico-chemical characterization of a VPO system obtained from boiler ash”, Applied Catalysis B: Environmental, 16:2 (1998), 139  crossref
    10. M.Yu. Sinev, P.A. Shiryaev, I.G. Mitov, D.G. Filkova, L.A. Petrov, Wang Ye, K. Otsuka, “Structure, redox properties and catalytic behavior of mixed iron-lithium molybdates”, Applied Catalysis A: General, 148:1 (1996), 41  crossref
    11. Tracey J. Hall, Justin S.J. Hargreaves, Graham J. Hutchings, Richard W. Joyner, Stuart H. Taylor, “Catalytic synthesis of methanol and formaldehyde by partial oxidation of methane”, Fuel Processing Technology, 42:2-3 (1995), 151  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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