Abstract:
Selectivity shifts from formaldehyde to ethane with oxygen pressure and temperature variation in methane oxidation over phosphate catalysts are evidence for the existence of mutual intermediate and different product selectivities over different catalysts under the same reaction conditions, indicating the participation of the surface in formaldehyde formation.1Fax: +7 095 938 2156.2Fax: +81 3 3729 0542.
Document Type:
Article
Language: English
Citation:
M. Yu. Sinev, S. Setiadi, K. Otsuka, “Selectivity Control by Oxygen Pressure in Methane Oxidation over Phosphate Catalysts”, Mendeleev Commun., 3:1 (1993), 10–11
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V. I. Lomonosov, M. Yu. Sinev, “Oxidative coupling of methane: Mechanism and kinetics”, Kinet Catal, 57:5 (2016), 647
S. Arndt, R. Schomäcker, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2014
M. Yu. Sinev, Z.T. Fattakhova, V.I. Lomonosov, Yu. A. Gordienko, “Kinetics of oxidative coupling of methane: Bridging the gap between comprehension and description”, Journal of Natural Gas Chemistry, 18:3 (2009), 273
Beata Michalkiewicz, Joanna Sreńscek-Nazzal, Piotr Tabero, Barbara Grzmil, Urszula Narkiewicz, “Selective methane oxidation to formaldehyde using polymorphic T-, M-, and H-forms of niobium(V) oxide as catalysts”, Chemical Papers, 62:1 (2008)
Mikhail Sinev, Vladimir Arutyunov, Andrey Romanets, Advances in Chemical Engineering, 32, Chemical Engineering Kinetics, 2007, 167
M. Yu. Sinev, “Free radicals as intermediates in catalytic oxidation of light alkanes: new opportunities”, Res. Chem. Intermed., 32:3-4 (2006), 205
Kiyoshi Otsuka, Ye Wang, “Direct conversion of methane into oxygenates”, Applied Catalysis A: General, 222:1-2 (2001), 145
L Alemany, “Catalytic activity in partial oxidation of methane and physico-chemical characterization of a VPO system obtained from boiler ash”, Applied Catalysis B: Environmental, 16:2 (1998), 139
M.Yu. Sinev, P.A. Shiryaev, I.G. Mitov, D.G. Filkova, L.A. Petrov, Wang Ye, K. Otsuka, “Structure, redox properties and catalytic behavior of mixed iron-lithium molybdates”, Applied Catalysis A: General, 148:1 (1996), 41
Tracey J. Hall, Justin S.J. Hargreaves, Graham J. Hutchings, Richard W. Joyner, Stuart H. Taylor, “Catalytic synthesis of methanol and formaldehyde by partial oxidation of methane”, Fuel Processing Technology, 42:2-3 (1995), 151