Abstract:
Cyclooctatetraenyldipropylborane 4 has been synthesized in 47% yield; activation parameters for bond shifting in 4 determined by lineshape analysis of the 13C NMR spectra are ΔG╪(298) = 67.7±0.1 kJ mol−1; ΔH╪ = 58.1±0.8 kJ mol−1; ΔS╪ = –32±5 kJ mol−1 K−1.
Document Type:
Article
Language: English
Citation:
M. E. Gurskii, I. D. Gridnev, A. V. Buevich, T. V. Potapova, V. I. Mstislavsky, A. O. Krasavin, Yu. N. Bubnov, “Synthesis and Dynamic Properties of Cyclooctatetraenyl(dipropyl)borane”, Mendeleev Commun., 4:6 (1994), 221–223
Linking options:
https://www.mathnet.ru/eng/mendc5228
https://www.mathnet.ru/eng/mendc/v4/i6/p221
This publication is cited in the following 2 articles:
Holger Braunschweig, Alexander Damme, Klaus Dück, Ivo Krummenacher, Valerie Paprocki, Krzysztof Radacki, Jacqueline Ramler, Carl Schiller, Christoph Schneider, “Boryl‐ and Silyl‐Substituted Mixed Sandwich Compounds of Scandium”, Chemistry A European J, 24:10 (2018), 2403
Stuart W. Staley, Russell A. Grimm, Gregory S. Martin, Rachel A. Sablosky, “Energetics of Bond Shift in Monohalogen-Substituted Cyclooctatetraenes”, Tetrahedron, 53:29 (1997), 10093
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