Abstract:
It has been shown by X-ray structure analysis, 1H NMR spectroscopy (including NOE) and PM3 calculations that symmetric isomers of the title compounds in the crystal and in solution have a Z,Z configuration stabilized by nN,π interaction, but not the E,E configuration suggested earlier.
Document Type:
Article
Language: English
Citation:
I. Yu. Bagryanskaya, Yu. V. Gatilov, M. M. Shakirov, A. V. Zibarev, “Z,Z Isomers of Sterically Hindered 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution”, Mendeleev Commun., 4:4 (1994), 136–137
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https://www.mathnet.ru/eng/mendc/v4/i4/p136
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I. Yu. Bagryanskaya, Yu. V. Gatilov, M. M. Shakirov, A. V. Zibarev, “The first stable R–N=S=N–H sulfur diimide”, Mendeleev Commun., 12:5 (2002), 167–168
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I. Yu. Bagryanskaya, Yu. V. Gatilov, A. V. Zibarev, “Molecular structure of 13-bis(2,6-dihalophenyl)-1,3-diaza-2-thiaallenes (2,6-Hal2C6H3-N=)2S in crystal (Hal = F, Cl)”, J Struct Chem, 40:4 (1999), 640
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I. Yu. Bagryanskaya, Yu. V. Gatilov, M. M. Shakirov, A. V. Zibarev, “Z,Z Isomers of Polyfluorinated 1,3-Bis(aryl)-1,3-diaza-2-thiaallenes, (ArN=)2S, in the Crystal and in Solution”, Mendeleev Commun., 4:5 (1994), 167–169
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