Abstract:
The Br2·nAIX3, CI2·nAIX3 and l2·nAIBr3 systems (X = Cl, Br, n = 1,2) have been found to actively catalyse cracking of C5–C12n–alkanes at room temperature.
Document Type:
Article
Language: English
Citation:
I. S. Akhrem, L. V. Afanas'eva, A. V. Orlinkov, M. E. Vol'pin, “Halogens (Cl2, Br2, I2) Activated by Aluminium Halides – Effective Initiators for Low-temperature Alkane Cracking”, Mendeleev Commun., 4:4 (1994), 131–133
Linking options:
https://www.mathnet.ru/eng/mendc5186
https://www.mathnet.ru/eng/mendc/v4/i4/p131
This publication is cited in the following 12 articles:
Irena Akhrem, Alexander Orlinkov, “Polyhalomethanes Combined with Lewis Acids in Alkane Chemistry”, Chem. Rev., 107:5 (2007), 2037
Irena Akhrem, Alexander Orlinkov, Sergei Vitt, Anatolii Chistyakov, “First examples of superelectrophile initiated iodination of alkanes and cycloalkanes”, Tetrahedron Letters, 43:7 (2002), 1333
A. L. Chistyakov, I. V. Stankevich, N. P. Gambaryan, I. S. Akhrem, “Mechanism of methane activation by electrophiles generated in the AlBr5 system: An MNDO/PM3 study of the potential energy surface of the [AlBr5+CH4] system”, Russ Chem Bull, 49:5 (2000), 799
I. S. Akhrem, A. V. Orlinkov, “Novel superelectrophilic complexes for low-temperature alkane and cycloalkane transformations”, Russ Chem Bull, 47:5 (1998), 740
A. L. Chistyakov, I. V. Stankevich, N. P. Gambaryan, I. S. Akhrem, “MNDO/PM3 study of the mechanism of a model reaction between methane and Br+ cation”, Russ Chem Bull, 47:9 (1998), 1666
Ilia Levitin, Vladimir Shur, “Mark Vol'pin: glorious path in science”, Inorganica Chimica Acta, 280:1-2 (1998), xv
I. S. Akhrem, I. M. Churilova, S. V. Vitt, A. V. Orlinkov, M. E. Vol'pin, “Functionalization of saturated hydrocarbons by aprotic superacids”, Russ Chem Bull, 46:3 (1997), 491
Ilia Levitin, Vladimir Shur, “Mark Vol'pin”, Inorganica Chimica Acta, 254:2 (1997), 203
Irena Akhrem, Svetlana Gudima, Mark Vol'pin, “Novel Sulfur‐Containing Inorganic Aprotic Superacids as Effective Initiators of Low‐Temperature Cracking and Isomerization of Alkanes”, Chemistry A European J, 2:7 (1996), 812
I. S. Akhrem, A. V. Orlinkov, L. V. Afanas'eva, M. E. Vol'pin, “Functionalization of saturated hydrocarbons by aprotic superacids 5. Regioselective carbonylation of propane in an organic solvent initiated by aprotic organic superacids CX4�nAlBr 3 (X = Br, Cl;n = 1 or 2)”, Russ Chem Bull, 45:5 (1996), 1154
A. L. Chistyakov, I. V. Stankevich, I. S. Akhrem, N. P. Gambaryan, M. E. Vol'pin, “Superelectrophiles generated in mBr2 nAlBr3 systems”, Mendeleev Commun., 6:5 (1996), 175–178
I. S. Akhrem, A. V. Orlinkov, M. E. Vol'pin, “Low-temperature functionalisation of alkanes and cycloalkanes by 'classical' and 'non-classical' (superacidic) Friedel–Crafts complexes”, Russian Chem. Reviews, 65:10 (1996), 849–863
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