Abstract:
The reaction of 2,4-diazido-s-triazines 1 with an equimolar amount or a two-fold molar excess of ethyl cyanoacetate in the presence of triethylamine in DMF affords the corresponding mono- 2 or diamino derivatives of s-triazine 3; on heating 2,4-diazido-s-triazines 1a–d with a two-fold molar excess of acetoacetone or ethyl acetoacetate in the presence of triethylamine in ethanol the corresponding 1,2,3-triazolo-s-triazines 4a–f are formed.
Document Type:
Article
Language: English
Citation:
Yu. A. Azev, I. P. Loginova, O. L. Guselnikova, S. V. Shorshnev, V. L. Rusinov, O. N. Chupakhin, “Reactions of Diazido Derivatives of s-Triazine with C-Nucleophiles”, Mendeleev Commun., 4:3 (1994), 104–107
Linking options:
https://www.mathnet.ru/eng/mendc5175
https://www.mathnet.ru/eng/mendc/v4/i3/p104
This publication is cited in the following 7 articles:
L. V. Batog, V. Yu. Rozhkov, M. I. Struchkova, A. S. Kulikov, N. N. Makhova, “Synthesis of N,N′-bis[4-(1H-1,2,3-triazol-1-yl)furazan-3-yl]-methylenediamine derivatives”, Russ Chem Bull, 62:6 (2013), 1391
Svetlana Mikhaylichenko, Anthony Veloso, Kunjal Patel, Vladimir Zaplishny, “Synthesis and structure of new 1,2,3-triazolyl substituted 1,3,5-triazines”, Eur. J. Chem., 3:1 (2012), 1
V. Yu. Rozhkov, L. V. Batog, M. I. Struchkova, “Synthesis of 1,2,4-oxadiazole-, pyrrole- and 1,2,3-triazole-substituted (1,2,3-triazol-1-yl)furazans”, Mendeleev Commun., 18:3 (2008), 161–163
L. V. Batog, V. Yu. Rozhkov, M. I. Struchkova, “Azido-1,2,5-oxadiazoles in reactions with 1,3-dicarbonyl compounds”, Mendeleev Commun., 12:4 (2002), 159–162
E. B. Nikolaenkova, V. P. Krivopalov, “Synthesis of 4,6-bis(1H-1,2,3-triazolyl)pyrimidines by the reaction of 4,6-diazido-2-(4-methoxyphenyl)-pyrimidine with compounds containing a reactive methylene group”, Chem Heterocycl Compd, 33:8 (1997), 968
Derek T. Hurst, Progress in Heterocyclic Chemistry, 7, 1995, 244
YU. A. AZEV, I. P. LOGINOVA, O. L. GUSELNIKOVA, S. V. SHORSHNEV, V. L. RUSINOV, O. N. CHUPAKHIN, “ChemInform Abstract: Reactions of Diazido Derivatives of s‐Triazine with C‐Nucleophiles.”, ChemInform, 25:43 (1994)
Contact us: