Abstract:
The enthalpy and entropy of activation in the homogeneous electrochemical reduction of phosphoric acid esters [(PhO)3–n(BuO)nPO, n = 0–2] are assumed to reflect transition state stabilization of the electron transfer step due to partial bonding between substrate and mediator.
Document Type:
Article
Language: English
Citation:
Yu. H. Budnikova, Yu. M. Kargin, A. I. Samosova, “Homogeneous Mediator Reduction of Arylalkylphosphates”, Mendeleev Commun., 4:2 (1994), 58–60
Linking options:
https://www.mathnet.ru/eng/mendc5152
https://www.mathnet.ru/eng/mendc/v4/i2/p58
This publication is cited in the following 2 articles:
Piret Villo, Andrey Shatskiy, Markus D. Kärkäs, Helena Lundberg, “Electrosynthetic C-O Bond Activation in Alcohols and Alcohol Derivatives”, Angew Chem Int Ed, 62:4 (2023)
Piret Villo, Andrey Shatskiy, Markus D. Kärkäs, Helena Lundberg, “Electrosynthetic C-O Bond Activation in Alcohols and Alcohol Derivatives”, Angewandte Chemie, 135:4 (2023)