Abstract:
Rapid degenerate hetero-(S,S)-Cope rearrangement of S-(1,2,3-triphenylcyclopropenyl)-O-ethyldithiocarbonate has been studied by use of dynamic 1H and 13C NMR methods and semiempirical PM3 calculations.
Document Type:
Article
Language: English
Citation:
I. E. Mikhailov, G. A. Dushenko, I. V. Dorogan, R. M. Minyaev, V. V. Negrebetsky, A. Zschunke, V. I. Minkin, “Hetero-Cope Rearrangement of S-(1,2,3-Triphenylcyclopropenyl)-O-ethyldithiocarbonate”, Mendeleev Commun., 4:1 (1994), 9–11
Linking options:
https://www.mathnet.ru/eng/mendc5129
https://www.mathnet.ru/eng/mendc/v4/i1/p9
This publication is cited in the following 9 articles:
G.A. Dushenko, I.E. Mikhailov, O.I. Mikhailova, R.M. Minyaev, V.I. Minkin, “STROENIE I?FLUKTUIRUYuSchEE POVEDENIE PENTAMETOKSIKARBONILTsIKLOPENTADIENA, “Doklady Akademii nauk””, Doklady Akademii Nauk, 2017, no. 6, 648
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Structure and fluxional behavior of pentamethoxycarbonylcyclopentadiene”, Dokl Chem, 476:2 (2017), 230
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Sigmatropic hydrogen shifts in aryltetraphenylcyclopentadienes”, Dokl Chem, 471:2 (2016), 350
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Mechanisms of circumambulatory rearrangements of 5-halogeno-1,2,3,4,5-pentamethoxycarbonylcyclopentadienes”, Russ Chem Bull, 64:9 (2015), 2043
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Mechanisms of rearrangements of substituted thiocyclopropenes”, Dokl Chem, 452:1 (2013), 220
Vladimir I. Minkin, Igor V. Dorogan, Ruslan M. Minyaev, “Computational modeling of the mechanisms and stereochemistry of circumambulatory rearrangements of formylcyclopropene and 4-hydroxycyclobutenyl cation”, J. Phys. Org. Chem., 13:1 (2000), 3
V. I. Minkin, I. E. Mikhailov, G. A. Dushenko, O. E. Kompan, A. Zschunke, “Fast and reversible migrations of N,S-centered groups around the perimeter of cyclopropene and cycloheptatriene rings”, Russ Chem Bull, 47:5 (1998), 884
G. A. Dushenko, I. E. Mikhailov, I. V. Dorogan, R. M. Minyaev, N. Hakam, A. Zschunke, V. I. Minkin, “Rapid and Reversible Migration of the Isothiocyanate Group around the Cyclopropene Ring”, Mendeleev Commun., 5:6 (1995), 213–215
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Muegge, V. I. Minkin, “Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate”, Mendeleev Commun., 5:4 (1995), 133–134
Contact us: