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Mendeleev Communications, 1994, Volume 4, Issue 1, Pages 5–7
DOI: https://doi.org/10.1070/MC1994v004n01ABEH000323
(Mi mendc5127)
 

This article is cited in 21 scientific papers (total in 21 papers)

Reactions of Samarium Atoms in Inert and Reactive Matrices

W. E. Klotzbuchera, M. A. Petrukhinab, G. B. Sergeevb

a Max-Planck-Institute fur Strahlenchemie, Mulheim a.d. Ruhr, Germany
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract: Cocondensation of samarium vapour with inert gases at cryogenic temperatures yields isolated samarium atoms and small clusters, while in complementary depositions with CO and N2 novel carbonyl and dinitrogen complexes are formed. Surprisingly, ‘naked’ samarium atoms can be observed at 9 K in pure dinitrogen.
Document Type: Article
Language: English


Citation: W. E. Klotzbucher, M. A. Petrukhina, G. B. Sergeev, “Reactions of Samarium Atoms in Inert and Reactive Matrices”, Mendeleev Commun., 4:1 (1994), 5–7
Linking options:
  • https://www.mathnet.ru/eng/mendc5127
  • https://www.mathnet.ru/eng/mendc/v4/i1/p5
  • This publication is cited in the following 21 articles:
    1. Attila Kovács, Werner Klotzbücher, “Preference of C2v Symmetry in Low-Spin Hexacarbonyls of Rare-Earth and f Elements”, Symmetry, 16:2 (2024), 178  crossref
    2. Attila Kovács, Werner Klotzbücher, “A DFT and Matrix–Isolation IR/UV-Visible Study of High-Coordinated Lanthanide-CO Complexes”, Molecules, 28:13 (2023), 5043  crossref
    3. Attila Kovács, Werner Klotzbücher, “Octa-coordination in complexes of lanthanides with N2 confirmed by matrix-isolation IR spectroscopy and DFT calculations”, Journal of Molecular Structure, 1272 (2023), 134222  crossref
    4. Jiaye Jin, Sudip Pan, Xiaoyang Jin, Shujun Lei, Lili Zhao, Gernot Frenking, Mingfei Zhou, “Octacarbonyl Anion Complexes of the Late Lanthanides Ln(CO)8- (Ln=Tm, Yb, Lu) and the 32‐Electron Rule”, Chemistry A European J, 25:13 (2019), 3229  crossref
    5. Hua Xie, Zhiling Liu, Xiaopeng Xing, Zichao Tang, “Infrared photodissociation spectroscopy of MO(CO)5+ (M = Sc, Y, La and Ce) in the gas phase”, Chemical Physics Letters, 628 (2015), 66  crossref
    6. Hua Xie, Jie Wang, Zhengbo Qin, Lei Shi, Zichao Tang, Xiaopeng Xing, “Octacoordinate Metal Carbonyls of Lanthanum and Cerium: Experimental Observation and Theoretical Calculation”, J. Phys. Chem. A, 118:40 (2014), 9380  crossref
    7. Peter G. Nelson, “Periodicity in the formulae of carbonyls and the electronic basis of the Periodic Table”, Found Chem, 15:2 (2013), 199  crossref
    8. G.B. Sergeev, K.J. Klabunde, Nanochemistry, 2013, 89  crossref
    9. Wenhua Xu, Xi Jin, Mohua Chen, Pekka Pyykkö, Mingfei Zhou, Jun Li, “Rare-earth monocarbonyls MCO: comprehensive infrared observations and a transparent theoretical interpretation for M = Sc; Y; La–Lu”, Chem. Sci., 3:5 (2012), 1548  crossref
    10. Athanassios C. Tsipis, Alexandros V. Stalikas, “Structural, electronic, and magnetoresponsive properties of triangular lanthanide clusters and their free‐standing nitrides”, J Comput Chem, 32:4 (2011), 620  crossref
    11. T. I. Shabatina, J. Mascetti, J. S. Ogden, G. B. Sergeev, “Competitive cryochemical reactions of transition metal atoms, clusters and nanosized particles”, Russian Chem. Reviews, 76:12 (2007), 1123–1137  mathnet  mathnet  crossref  isi  scopus
    12. Nanochemistry, 2006, 215  crossref
    13. Xi Jin, Ling Jiang, Qiang Xu, Mingfei Zhou, “Reactions of Gadolinium Atoms and Dimers with CO:  Formation of Gadolinium Carbonyls and Photoconversion to CO Activated Molecules”, J. Phys. Chem. A, 110:46 (2006), 12585  crossref
    14. Mingfei Zhou, Xi Jin, Jun Li, “Reactions of Cerium Atoms and Dicerium Molecules with CO:  Formation of Cerium Carbonyls and Photoconversion to CO-Activated Insertion Molecules”, J. Phys. Chem. A, 110:34 (2006), 10206  crossref
    15. A. V. Vlasov, T. I. Shabatina, A. Yu. Ivanov, G. G. Sheina, A. V. Nemukhin, G. B. Sergeev, “Interaction of lanthanide atoms with 4-pentyl-4'-cyanobiphenyl in low-temperature condensates”, Mendeleev Commun., 15:1 (2005), 10–11  mathnet  crossref
    16. John R. Lombardi, Benjamin Davis, “Periodic Properties of Force Constants of Small Transition-Metal and Lanthanide Clusters”, Chem. Rev., 102:6 (2002), 2431  crossref
    17. W.E. Klotzbücher, M.A. Petrukhina, A.V. Nemukhin, A.Yu. Ermilov, B.L. Grigorenko, “Formation of mixed d- and f-block metal clusters in inert matrices: comparison of the observed and theoretical optical spectra of AgHo”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 57:5 (2001), 1093  crossref
    18. Stephen P. Willson, Lester Andrews, “Characterization of the Reaction Products of Laser-Ablated Late Lanthanide Metal Atoms with Dinitrogen. Matrix IR Spectra of LnN, (LnN)2, and Ln(NN)x Molecules”, J. Phys. Chem. A, 103:10 (1999), 1311  crossref
    19. A. Yu. Ermilov, A. V. Nemukhin, V. M. Kovba, “Characterization of structures and spectra of holmium complexes formed in the CO and N2 matrices”, Mendeleev Commun., 9:3 (1999), 88–90  mathnet  crossref
    20. A.V. Nemukhin, A.Yu. Ermilov, M.A. Petrukhina, W.E. Klotzbücher, J. Smets, “Predicting lanthanide cluster properties: a comparison with the observed optical spectra of Ho2”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 53:11 (1997), 1803  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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