Abstract:
A cyclic voltammetry study of the η5-pentamethylcyclopentadienylrhodium (Cp*Rh) complexes [(Cp*Rh)2(μ.-Cl)3]+ and [Cp*RhIIIaq]2+ at pH 6.05 in the absence and in the presence of nicotinamide cofactors indicates that the chloro complex is more advantageous for electrochemical reduction of NAD+ into NADH; the reverse oxidation of NADH by [(Cp*Rh)2(μ-CI)3]+ is insufficiently selective for practical applications according to the 1H NMR data.
Document Type:
Article
Language: English
Citation:
U. Koelle, A. D. Ryabov, “The Effect of Chloride on the Electroreduction of NAD+ in the Presence of [Cp*RhIII]2+ Species”, Mendeleev Commun., 5:5 (1995), 187–189
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https://www.mathnet.ru/eng/mendc/v5/i5/p187
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Richard H. Fish, “Bioorganometallic chemistry: synthesis, structure, and molecular recognition chemistry of (η5-pentamethylcyclopentadienyl)rhodium–DNA/RNA complexes in water”, Coordination Chemistry Reviews, 185-186 (1999), 569
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