Abstract:
Unlike 5-(1,2,3,4,5-pentaphenylcyclopentadienyl)isothiocyanate, its selenium analogue 5-(1,2,3,4,5-pentaphenylcyclopenta-dienyl)isoselenocyanate exists in solution in an equilibrium with the isomeric seienocyanate, both isomers being found to undergo circumambulatory rearrangements.
Document Type:
Article
Language: English
Citation:
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Muegge, R. V. Skachkov, V. I. Minkin, “Synthesis and Rearrangements of 5-(1,2,3,4,5-Pentaphenylcyclopentadienyl)-isoselenocyanate”, Mendeleev Commun., 5:5 (1995), 182–184
Linking options:
https://www.mathnet.ru/eng/mendc5088
https://www.mathnet.ru/eng/mendc/v5/i5/p182
This publication is cited in the following 7 articles:
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Structure and Rearrangements of 7-(Heptaphenylcycloheptatrienyl)isochalcogencyanates”, Russ J Org Chem, 54:8 (2018), 1134
G.A. Dushenko, I.E. Mikhailov, O.I. Mikhailova, R.M. Minyaev, V.I. Minkin, “STRUKTURA I PEREGRUPPIROVKI 7-(GEPTAFENILTsIKLOGEPTATRIENIL)IZOKhALKOGENTsIANATOV, “Zhurnal organicheskoi khimii””, Zhurnal organicheskoi khimii, 2018, no. 8, 1127
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Structural and stereochemical nonrigidity of 7-(heptaphenylcycloheptatrienyl) isothiocyanate”, Dokl Chem, 466:2 (2016), 35
Janet E. Hack, Joel F. Liebman, Patai's Chemistry of Functional Groups, 2013
Sergei M. Lukyanov, Alla V. Koblik, Patai's Chemistry of Functional Groups, 2009
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, G. Reck, B. Schulz, V. I. Minkin, “Structure and rearrangements of 7-(1,2,3,4,5,6,7-heptaphenylcycloheptatrienyl) isocyanate, isothiocyanate and isoselenocyanate”, Mendeleev Commun., 9:6 (1999), 222–225
Vladimir I. Minkin, Ruslan M. Minyaev, Igor V. Dorogan, “Computational modeling of the mechanisms of circumambulatory rearrangements of main-group migrants in the cyclopropene ring”, Journal of Molecular Structure: THEOCHEM, 398-399 (1997), 237