This article is cited in 3 scientific papers (total in 3 papers)
Regio- and Stereoselective Preparation of 3-Trimethylsilylallylic Alcohols by Solvolysis of 2-Trimethylsilylic Derivatives of 1-Bromo- and 1,1-Dibromocyclo-propanes in the Presence of CuSO4
Abstract:
The interaction of 1-bromo- and 1,1-dibromocyclopropanes with an equimolar quantity of CuSO4 in a DMSO–water mixture (molar ratio halocyclopropane:CuSO4·5H2O:DMSO:H2O = 1:1:10–12:14–16) proceeds via cleavage of the three-membered ring to selectively give the most thermodynamically stable isomers of the corresponding 3-trimethylsilyl-substituted allylic or 2-bromoallylic alcohols.
Document Type:
Article
Language: English
Citation:
O. S. Korneva, L. G. Menchikov, E. S. Koltun, O. M. Nefedov, “Regio- and Stereoselective Preparation of 3-Trimethylsilylallylic Alcohols by Solvolysis of 2-Trimethylsilylic Derivatives of 1-Bromo- and 1,1-Dibromocyclo-propanes in the Presence of CuSO4”, Mendeleev Commun., 5:4 (1995), 135
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https://www.mathnet.ru/eng/mendc/v5/i4/p135
This publication is cited in the following 3 articles:
Km Kajol, Chintakunta Ramesh, “Sequential One‐pot Method for the Synthesis of 4‐(Hydroxymethyl)oxazoles and their Application in Phosphonates Synthesis”, Asian J Org Chem, 10:3 (2021), 649
O. S. KORNEVA, L. G. MENCHIKOV, E. S. KOLTUN, O. M. NEFEDOV, “ChemInform Abstract: Regio‐ and Stereoselective Preparation of 3‐Trimethylsilylallylic Alcohols by Solvolysis of 2‐Trimethylsilylic Derivatives of 1‐Bromo‐ and 1,1‐Dibromocyclopropanes in the Presence of CuSO4.”, ChemInform, 26:48 (1995)
L. G. Menchikov, A. V. Vorogushin, O. S. Korneva, O. M. Nefedov, “An Effective Method for Alcohol Preparation by Hydrolysis of Organohalides in the Presence of Copper and its Salts in Aqueous DMSO”, Mendeleev Commun., 5:6 (1995), 223–224
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