aDepartment of Chemistry, Southwest University of Science and Technology, Mianyang, P.R. China bXi'an Modern Chemistry Research Institute, Xi'an, P.R. China cSchool of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, P.R. China
Abstract:
The nitrogen–nitrogen double bond between two molecules of 3,5-diamino-1H-1,2,4-triazole is successfully constructed using a one-step electrochemical coupling method. The oxidation occurs selectively when the electrochemical parameters are properly adjusted to provide a yield of 45.77%. Subsequently, the oxidative coupling of this substrate with electrochemically generated hydroxy nickel oxide or sodium hypochlorite is verified.
Keywords:
electrochemical synthesis, conjugation reaction, active site, clean and efficient, triazoles, azo compounds, voltage control.
Citation:
M. Xie, J. Gong, J. Zhou, J. Wang, Yu. Cao, T. Zhou, Ya. Dai, “Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound”, Mendeleev Commun., 33:5 (2023), 717–720
Linking options:
https://www.mathnet.ru/eng/mendc505
https://www.mathnet.ru/eng/mendc/v33/i5/p717
This publication is cited in the following 2 articles:
Jiachen Li, Yang Li, Yuqiang Ma, Zihang Zhao, Huarong Peng, Tao Zhou, Ming Xu, Daidi Fan, Haixia Ma, Jieshan Qiu, Zhengxiao Guo, “Electrochemical N–N Oxidatively Coupled Dehydrogenation of 3,5-Diamino-1H-1,2,4-triazole for Value-Added Chemicals and Bipolar Hydrogen Production”, J. Am. Chem. Soc., 2025
M. N. Elinson, A. N. Vereshchagin, Yu. E. Ryzhkova, F. V. Ryzhkov, “Electrochemical transformations of CH-acids”, Mendeleev Commun., 34:2 (2024), 145–155
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