Abstract:
Reaction of aniline, o- and m-substituted anilines or N,N-dialkylanilines with bromine and nitrosonium hydrogensulfate in concentrated sulfuric acid leads to the corresponding 4-bromoanilines but no bromination takes place in the absence of nitrosonium salt.
Document Type:
Article
Language: English
Citation:
M. V. Gorelik, V. I. Lomzakova, E. A. Khamidova, V. Ya. Shteiman, M. G. Kuznetsova, A. M. Andrievsky, “Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid”, Mendeleev Commun., 5:2 (1995), 65–66
Linking options:
https://www.mathnet.ru/eng/mendc5034
https://www.mathnet.ru/eng/mendc/v5/i2/p65
This publication is cited in the following 2 articles:
Te Hu, Ian Baxendale, Marcus Baumann, “Exploring Flow Procedures for Diazonium Formation”, Molecules, 21:7 (2016), 918
M. V. Gorelik, V. I. Lomzakova, E. A. Khamidova, V. Ya. Shteiman, M. G. Kuznetsova, “Interaction of Aniline with Diazotising and Nitrating Agents in Concentrated Sulfuric Acid”, Mendeleev Commun., 5:2 (1995), 64–65
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