Abstract:
Tetrahydropyran (THP) forms a clathrate hydrate THP·17H2O of cubic structure II which melts at P = 1 atm, T= – 0.8°C decomposing into two liquids with an upper consolute temperature of dissolution of 226 °C. It is destabilized by pressure and at P > 1.15 kbar, T= – 4.3°C cubic structure I hydrate appears to become stable.
Document Type:
Article
Language: English
Citation:
Yu. A. Dyadin, T. V. Mikina, F. V. Zhurko, Yu. I. Mironov, A. V. Manuilov, G. Skripko, “Clathrate Hydrates in the Water–Tetrahydropyran System at High Pressure”, Mendeleev Commun., 5:2 (1995), 62–63
Linking options:
https://www.mathnet.ru/eng/mendc5032
https://www.mathnet.ru/eng/mendc/v5/i2/p62
This publication is cited in the following 4 articles:
Jiwoong Seol, “Large Guest Molecules Selectively Forming sII- or sH-Type Hydrates: Chameleon-Like Behavior”, J. Phys. Chem. Lett., 2025, 2433
H. Nelson, A. Ihrig, R. Kahlau, P. Kibies, S.M. Kast, R. Böhmer, “Deuteron magnetic resonance and dielectric studies of guest reorientation and water dynamics in six clathrate hydrates containing ring-type guests”, Journal of Non-Crystalline Solids, 407 (2015), 431
Waldemar Kulig, Piotr Kubisiak, Lukasz Cwiklik, “Steric and Electronic Effects in the Host-Guest Hydrogen Bonding in Clathrate Hydrates”, J. Phys. Chem. A, 115:23 (2011), 6149
Chemical Industries, 20074156, Clathrate Hydrates of Natural Gases, Third Edition, 2007, 45
Contact us: